Name: Ammonium fluoride 40 % solution
Brand: Fujairah Chemical
Availability: InStock

Part No: RXSOL-81-6212-400

Ammonium fluoride 40 % solution

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Part No: RXSOL-81-6212-400

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Safety data (MSDS)

Porduct Name	Ammonium fluoride 40 % solution
Part Number	RXSOL-81-6212-400

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA

Phone	+91 22 20871200 - 1400
Fax	+91 22 27612100 :::AOH :0091 9821214367
Email	mail@rxmarine.com
Website	www.rxmraine.com

Chemical Name	Cas No	EC No	Whight	Formula
Ammonium fluoride for analysis EMSURE® ACS	12125-01-8	235-185-9	37,04 g/mol	NH₄F

Signal Word	Danger
Hazard Statements	H300 + H310 Fatal if swallowed or in contact with skin.
Precautionary statements	P262 Do not get in eyes, on skin, or on clothing. P280 Wear protective gloves/ protective clothing. P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P302 + P352 + P310 IF ON SKIN: Wash with plenty of water. Immediately call a POISON CENTER/ doctor.
Classification of the substance or mixture	Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008.
Supplemental Hazard Statements	None
Other hazards	This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

General advice	Countermeasurements must be implemented at once. First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance.
If inhaled	After inhalation: fresh air. Immediately call in physician. Keep respiratory tract clear. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.
Eye Contact	After contact with eyes: Rinse with plenty of water keeping eyelids open, protecting the unaffected eye (at least 10 minutes). Seek medical advice immediately! Remove contact lenses.
Swallowed	After swallowing: Immediately give to drink plenty of water, add calcium (in the form of calcium gluconate or calcium lactate). Caution: In the case of vomiting risk of perforation! Administer more calcium gluconate solution. Laxative: Sodium sulfate (1 tablespoon/1/4 l water). Seek medical advice immediately. Ensure that injured persons remain calm and protect them against heat loss.
Skin Contact	After contact with skin: Rinse with plenty of water for at least 10 minutes. Immediately remove contaminated clothes. Apply calcium gluconate gel (preparation: boil 5 g of calcium gluconate in 85 ml of hot distilled water, add 10 g glycerol. Allow 5 g of Carmellose-sodium to swell in the hot solution. Stable for 6 months, store in a cool place) and massage into the skin until the pain subsides, in between rinse with water and apply fresh gel. Continue gel therapy for another 15 minutes after the pain has subsided. If no calcium gluconate gel is available, apply several dressings thoroughly moistened with 20 % calcium gluconate solution. Medical advice absolutely required! Call a physician immediately.
Inhalation	Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary.
Ingestion	Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Most important symptoms and effects, both acute and delaye	The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
Indication of any immediate medical attention and special treatment needed	Note for the doctor: It is recommended to consult a doctor with experience in the treatment of lesions caused by hydrofluoric acid. If a systemic effect is suspected, monitoring and treatment in an intensive care unit is urgently required. Caution, ventricular fibrillation due to electrolyte imbalance.

Flammability	May be combustible at high temperature.
Suitable extinguishing media	For this substance/mixture no limitations of extinguishing agents are given.
Unsuitable extinguishing media	Do NOT use water jet.
Special hazards arising from the substance or mixture	Nitrogen oxides (NOx) Hydrogen fluoride Not combustible. Fire may cause evolution of: Ammonia, Hydrogen fluoride Ambient fire may liberate hazardous vapours.
Further information	Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
Hazardous combustion products	Fire may cause the evolution of Sulphur oxides, nitrogen oxides.
Advice for firefighters	Wear self-contained breathing apparatus for firefighting if necessary.
Protective Equipment	Use personal protective equipment.
Specific Hazards Arising from the Chemical	Has a fire-promoting effect due to the release of oxygen. Ambient fire may liberate hazardous vapours.

Personal precautions, protective equipment and emergency procedures	Advice for non-emergency personnel: Avoid generation and inhalation of dusts in all circumstances. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.
Spillage	Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal.
Personal Protection	Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8.
Enviromental Precaution	Do not let product enter drains.
Methods and materials for containment and cleaning	Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully. Dispose of properly. Clean up affected area. Avoid generation of dusts.
Reference to other sections	For disposal see section 13.

Advice on protection against fire and explosion	Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge.
Incompatible materials	Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills.
Hygiene measures	Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2.
Advice on safe handling	Work under hood. Do not inhale substance/mixture.
Conditions for safe storage, including any incompatibilities	Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons. Moisture sensitive.
Storage conditions	Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons. Recommended storage temperature see product label.
Storage class	Storage class (TRGS 510): 6.1D: Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
Specific end use(s)	Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
Advice on general occupational hygiene	Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance.

Exposure controls	No specific additional engineering controls are required. Provide good natural or artificial ventilation.
Engineering Control	Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Eye/face protection	Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Body Protection	protective clothing
Skin protection	Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. Full contact Material: butyl-rubber Minimum layer thickness: 0,3 mm Break through time: 480 min Material tested:Butoject® (KCL 897 / Aldrich Z677647, Size M) Splash contact Material: Chloroprene Minimum layer thickness: 0,6 mm Break through time: 30 min Material tested:Camapren® (KCL 722 / Aldrich Z677493, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the EC approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Respiratory protection	Recommended Filter type: Filter B-(P3) The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Other Protection Measure	Handle in accordance with good industrial hygiene and safety practice.
Control of environmental exposure	Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Physical state	solid
Colour	white
Odour	ammoniacal
Odor Threshold	Not Applicable
pH	ca.6 at 50 g/l at 20 °C
Melting Point	-93 °C - lit.
Boiling Point	97 °C - lit.
Flash Point	6 °C - closed cup
Evaporation Rate	Not Applicable
Flammability (solid, gas)	No data available
Explosive limits	No Data Available
Upper/lower flammability or explosive limits	No data available
Autoignition temperature	No data available
Decomposition temperature	ca. 100 °C
Vapour pressure	No data available
Viscosity	No data available
Density	0,772 g/mL at 25 °C - lit.
Relative Density	No data available
Specific Gravity	No data available
Partition coefficient	No data available
Explosive properties	No data available
Solubility	820 g/l at 20 °C
Ignition temperature	No information available.
Particle characteristics	No data available

Reactivity	No data available
Chemical stability	The product is chemically stable under standard ambient conditions (room temperature) .
Possibility of hazardous reactions	Generates dangerous gases or fumes in contact with:acids Release of: Hydrogen fluoride Risk of explosion with: halogen-halogen compounds
Conditions to avoid	hygroscopic no information available
Incompatible materials	glass, Metals, quartzes/silicate ceramics
Hazardous decomposition products	In the event of fire: see section 5

Acute toxicity	Acute toxicity estimate Oral - 100,1 mg/kg (Expert judgment) Acute toxicity estimate Inhalation - 0,6 mg/l - dust/mist (Expert judgment) Acute toxicity estimate Dermal - 300,1 mg/kg (Expert judgment)
Skin corrosion/irritation	No data available
Serious eye damage/irritation	No data available
Respiratory or skin sensitization	No data available
Carcinogenicity	No data available
Germ cell mutagenicity	Test Type: Ames test Test system: Salmonella typhimurium Result: negative Remarks: (National Toxicology Program)
Reproductive toxicity	No data available
Specific target organ toxicity - single exposure	No data available
Additional Information	RTECS: UF9625000 Lung irritation, Cyanosis, Central nervous system depression To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Persistence and degradability	No data available
Toxicity to fish	Static test LC50 - Oncorhynchus mykiss (rainbow trout) - 75 mg/l - 96 h (OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrates	Static test EC50 - Daphnia magna (Water flea) - 42,81 mg/l - 48 h (OECD Test Guideline 202) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: maleic acid
Toxicity	Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 1.520 mg/l - 96 h
Toxicity to bacteria	EC10 - Bacteria - 14 mg/l - 72 h Remarks: (Lit.) EC5 - E.coli - 15.000 mg/l Remarks: (Lit.) (maximum permissible toxic concentration)
Toxicity to algae	Static test ErC50 - Pseudokirchneriella subcapitata (green algae) - 74,35 mg/l - 72 h (OECD Test Guideline 201) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: maleic acid
Products Biodegradation	The methods for determining the biological degradability are not applicable to inorganic substances.
Mobility in soil	No data available
Results of PBT and vPvB assessment	This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting properties	No data available
Other adverse effects	No data available .

Product

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UN number	ADR/RID:2505 IMDG:2505 IATA: 2505
UN proper shipping name	ADR/RID:AMMONIUM FLUORIDE IMDG:AMMONIUM FLUORIDE IATA:AMMONIUM FLUORIDE
Transport hazard class(es)	ADR/RID:6.1 IMDG: 6.1 IATA:6.1
Packaging group	ADR/RID: III IMDG: III IATA:III
Environmental hazards	ADR/RID: No IMDG: No IATA: No
Special precautions for user	No data available
Further information	Not classified as dangerous in the meaning of transport regulations.

Safety, health and environmental regulations/legislation specific for the substance or mixture	This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
Other regulations	Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment	For this product a chemical safety assessment was not carried out

Other Information

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.