Name: HEXAMETHYLENEIMINE
Brand: Fujairah Chemical
Availability: InStock

Part No: RXSOL-19-1314-025

A colorless liquid with an ammonia-like odor. It is also used as a intermediate for agrochemicals, zeolites, dyes , inks, rubber chemicals, textile chemicals, corrosion inhibitors, ore flotation etc

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Part No: RXSOL-19-1314-025

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Safety data (MSDS)

Product Name	HEXA METHYLENEIMINE
Part Number	RXSOL-19-1314-025

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA

Phone	+91 22 20871200 - 1400
Fax	+91 22 27612100 :::AOH :0091 9821214367
Email	mail@rxmarine.com
Website	www.rxmraine.com

Chemical Name	CAS	EC number	Weight	Formula
Hexamethyleneimine	111-49-9	203-875-9	= 100 %	C₆H₁₃N

Signal Word	Danger
Hazard Statements	H225 Highly flammable liquid and vapor. H300 Fatal if swallowed. H314 Causes severe skin burns and eye damage. H331 Toxic if inhaled. H335 May cause respiratory irritation.
Precautionary statements	P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Classification of the substance or mixture	Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008.
Supplemental Hazard Statements	None.
Other hazards	This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Ecological information: The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Toxicological information: The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

General advice	First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance.
If inhaled	After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.
Eye Contact	After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.
Swallowed	If swallowed: give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible. Do not attempt to neutralise.
Skin Contact	In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.
Inhalation	Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary.
Ingestion	Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Most important symptoms and effects, both acute and delaye	The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
Indication of any immediate medical attention and special treatment needed	No data available

Flammability	May be combustible at high temperature.
Suitable extinguishing media	Carbon dioxide (CO2) Foam Dry powder
Unsuitable extinguishing media	For this substance/mixture no limitations of extinguishing agents are given..
Special hazards arising from the substance or mixture	Carbon oxides Nitrogen oxides (NOx) Combustible. Pay attention to flashback. Vapors are heavier than air and may spread along floors. Development of hazardous combustion gases or vapours possible in the event of fire. Forms explosive mixtures with air at ambient temperatures.
Further information	Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
Hazardous combustion products	Fire may cause the evolution of Sulphur oxides, nitrogen oxides.
Advice for firefighters	Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Protective Equipment	Use personal protective equipment.
Specific Hazards Arising from the Chemical	Has a fire-promoting effect due to the release of oxygen. Ambient fire may liberate hazardous vapours.

Personal precautions, protective equipment and emergency procedures	Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.
Spillage	Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal.
Personal Protection	Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8.
Enviromental Precaution	Do not let product enter drains. Risk of explosion.
Methods and materials for containment and cleaning	Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area.

Advice on protection against fire and explosion	Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge..
Incompatible materials	Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills.
Hygiene measures	Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2.
Precautions for safe handling	Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.
Conditions for safe storage, including any incompatibilities	Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.
Storage conditions	Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorized persons.
Storage class	Storage class (TRGS 510): 3: Flammable liquids
Specific end use(s)	Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
Advice on general occupational hygiene	Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance.
Requirements for storage	Keep in cool and store under shade.

Exposure controls	No specific additional engineering controls are required. Provide good natural or artificial ventilation.
Engineering Control	Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Eye/face protection	Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles
Body Protection	Flame retardant antistatic protective clothing.
Skin protection	This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: butyl-rubber Minimum layer thickness: 0,7 mm Break through time: 30 min Material tested:Butoject® (KCL 898) Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril®
Respiratory protection	Recommended Filter type: Filter type B The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Other Protection Measure	Handle in accordance with good industrial hygiene and safety practice.
Control of environmental exposure	Do not let product enter drains. Risk of explosion.

Physical state	Clear, liquid
Colour	Colorless
Odour	Amine-like
Odor Threshold	Not Applicable
pH	No data available
Melting Point	-37 °C
Boiling Point	138 °C at 999 hPa - lit.
Flash Point	No data available
Evaporation Rate	Not Applicable
Flammability (solid, gas)	No data available
Explosive limits	No Data Available
Upper/lower flammability or explosive limits	No data available
Autoignition temperature	No data available
Decomposition temperature	> 300 °C
Viscosity,kinematic	No data available
Vapour pressure	12,5 hPa at 20 °C
Density	0,88 g/cm3 at 25 °C - lit.
Relative Vapour Density	3,43 - (Air = 1.0)
Freezing point	No data available
Specific Gravity	No data available
Partition coefficient	log Pow: 1,7 at 20 °C
Explosive properties	No data available
Solubility	at 20 °C soluble
Ignition temperature	No information available.
Particle characteristics	No data available

Reactivity	Vapors may form explosive mixture with air.
Stability	The product is chemically stable under standard ambient conditions (room temperature) .
Possibility of hazardous reactions	Violent reactions possible with: Strong oxidizing agents Strong acids
Conditions to avoid	Warming.
Incompatible materials	No data available
Hazardous Polymerization	In the event of fire: see section 5

Acute toxicity	LD50 Oral - Rat - 410 mg/kg Remarks: (External MSDS) Symptoms: If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach. LD50 Oral - Rat - 20,7 mg/kg Remarks: Behavioral:Food intake (animal). Lungs, Thorax, or Respiration:Pulmonary emboli. Liver:Other changes. LC50 Inhalation - Mouse - 2 h - 10.800 mg/m3 Dermal: No data available
Skin corrosion/irritation	Skin - Rabbit Result: Corrosive after 1 to 4 hours of exposure - 4 h Remarks: (ECHA)
Serious eye damage/eye irritation	Eyes - Rabbit Result: Causes burns. Remarks: (Lit.) Remarks: Causes serious eye damage.
Respiratory or skin sensitization	No data available
Carcinogenicity	No data available
Germ cell mutagenicity	Test Type: Ames test Test system: Escherichia coli/Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Test Type: Mutagenicity (mammal cell test): chromosome aberration. Test system: Human lymphocytes Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 473 Result: negative
Reproductive toxicity	No data available
Specific target organ toxicity - single exposure	Inhalation - May cause respiratory irritation. - Respiratory system
Special Remarks on other Toxi Effects on Humans	Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism.
Additional Information	The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Repeated dose toxicity - Rat - male and female - Oral - NOAEL (No observed adverse effect level) - 50 mg/kg RTECS: CM3150000 Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Cough, Shortness of breath, Headache, Nausea To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice.

Persistence and degradability	Biodegradability Result: > 60 % - Moderately (partly) eliminable (DOC reduction 20- 70 %). (OECD Test Guideline 302B) Remarks: (External MSDS)
Bioaccumulative potential	No data available
Toxicity to fish	Flow-through test LC50 - Oncorhynchus mykiss (rainbow trout) - > 100 mg/l - 96 h (OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrates	Flow-through test EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h (OECD Test Guideline 202)
Toxicity to algae	Static test ErC50 - Selenastrum capricornutum (green algae) - 88 mg/l - 72 h (OECD Test Guideline 201) static test NOEC - Selenastrum capricornutum (green algae) - 10 mg/l - 72 h (OECD Test Guideline 201)
Toxicity to bacteria	EC5 - Bacteria - 127 mg/l Remarks: (Hommel)
Mobility in soil	No Information available
Results of PBT and vPvB assessment	This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting properties	The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Other adverse effects	Biological effects: Forms corrosive mixtures with water even if diluted. Discharge into the environment must be avoided.

Disposal methods	The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging	Dispose of as unused product.
Waste treatment Method	No data available .

UN number	ADR/RID: 2493 IMDG: 2493 IATA: 2493
UN proper shipping name	ADR/RID:Hexamethyleneimine IMDG: Hexamethyleneimine IATA:Hexamethyleneimine
Transport hazard class(es)	ADR/RID: 3 (8) IMDG: 3 (8) IATA: 3 (8)
Packaging group	ADR/RID: II IMDG: II IATA: II
Environmental hazards	ADR/RID: No IMDG: No IATA: No
Special precautions for user	Tunnel restriction code : (C/E)
Further information	Not classified as dangerous in the meaning of transport regulations.
Transport in bulk according to IMOinstruments	No data available

Inventory status	Components are on the following inventories: Polymaleic acid: - US TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean, Philippine PICCS and Chinese Xi irritant R 36/38 Irritant to eyes & skin R 41 Risk of serious damage to eyes S24/25 Avoid contact with skin and eyes S26/28 In case of contact eyes & skin, rinse with plenty water and seek medical advice Section 312/313: Not listed. Not listed under California proposition 65.
Safety, health and environmental regulations/legislation specific for the substance or mixture	This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
National legislation	Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. H2 ACUTE TOXIC P5c FLAMMABLE LIQUIDS
Other regulations	Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment	For this product a chemical safety assessment was not carried out

Other Information

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if RX Marine International has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

PRODUCT NAME	:	HEXAMETHYLENEIMINE
CAS number	:	111-49-9
UN number	:	2493
Formula	:	C6H12NH
Odour	:	AMMONIA LIKE
Solubility in water	:	COMPLETE
Density	:	0.879 at 20 ^oC
Boiling point	:	138 ^oC
Melting point	:	-37 ^oC
Viscosity	:
Flashpoint	:
Explosive limits	:
Vapour pressure	:
Skin absorption/irritation	:	YES
TLV Country	:
Pollution category 1994	:	C

HEXAMETHYLENEIMINE

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