
|
Product Name |
Morpholine |
|
Part Number |
RXSOL-40-1382-210 |
|
Synonym |
Tetrahydro-2H-1,4-oxazine |
|
Chemical Formula |
C4H9NO |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

|
Name
|
CAS #
|
% by Weight
|
Chem Formula |
R Phrases |
|
Morpholine
|
110-91-8
|
100
|
C4H9NO |
R10 R20/21/22 R34 |
Toxicological Data on Ingredients : Morpholine: ORAL (LD50): Acute: 1450 mg/kg [Rat]. 525 mg/kg [Mouse]. DERMAL (LD50): Acute: 500 mg/kg [Rabbit].
VAPOR (LC50): Acute: 11313.7 ppm 4 hour(s) [Rat].

|
Potential Acute Health Effects |
Very hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation. Corrosive to skin and eyes on contact. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or,occasionally, blistering. |
|
Potential Chronic Health Effects |
445°C (833°F)Very hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of
ingestion, of inhalation.CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS:Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs, mucous membranes. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation.Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated or prolonged inhalation of vapors may lead to chronic respiratory irritation. |

|
Eye Contact |
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Do not use an eye ointment. Seek medical attention. |
|
Skin Contact |
If the chemical got onto the clothed portion of the body, remove the contaminated clothes as quickly as possible, protecting your own hands and body. Place the victim under a deluge shower. If the chemical got on the victim's exposed skin, such as the hands : Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin.Cold water may be used. If irritation persists, seek medical attention. Wash contaminated clothing before reusing. |
|
Serious Skin Contact |
Wash with a disinfectant soap and cover the contaminated skin with an anti bacterial cream. Seek immediate medical attention. |
|
Inhalation |
Allow the victim to rest in a well ventilated area. Seek immediate medical attention. |
|
Serious Inhalation |
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention. |
|
Ingestion |
Do not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention. |
|
Serious Ingestion |
Not available. |

|
Flammability of the Product |
Flammable. |
|
Auto-Ignition Temperature |
310°C (590°F) |
|
Flash Points |
CLOSED CUP: 35°C (95°F) OPEN CUP: 38°C (100.4°F). |
|
Flammable Limits |
LOWER: 1.8% UPPER: 11.2% |
|
Products of Combustion |
These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).Fire Hazards in Presence of Various Substances:Not available Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. |
|
Fire Fighting Media and Instructions |
Flammable liquid, soluble or dispersed in water. |
|
SMALL FIRE |
Use DRY chemical powder. |
|
LARGE FIRE |
Use alcohol foam, water spray or fog. Cool containing vessels with water jet in order to prevent pressure build-up, auto ignition or explosion. |
|
Special Remarks on Fire Hazards |
Not available. |
|
Special Remarks on Explosion Hazards |
Not Available |

|
Small Spill |
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. |
|
Large Spill |
Flammable liquid. Corrosive liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if witout risk. Absorb with DRY earth, sand or other non combustible material. Do not get water inside container. Do not touch spilled material.Use water spray curtain to divert vapor drift. Prevent entry into sewers, basements confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal. Be careful that the product is not present at a concentration level above TLV.Check TLV on the MSDS and with local authorities. |

|
Precautions
|
Keep container dry. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapour/spray. Never add water to this product In case of insufficient ventilation, wear suitable respiratory equipment If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes
|
|
Storage
|
Flammable materials should be stored in a separate safety storage cabinet or room.
Keep away from heat. Keep away from sources of ignition. Keep container tightly closed. Keep in a cool, well-ventilated place. Ground all equipment containing material.A refrigerated room would be preferable for materials with a flash point lower than37.8°C (100°F).
|

|
Engineering Control
|
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
|
|
Personal Protection
|
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
|
|
Personal Protection in Case of a Large Spill
|
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
|
|
Exposure Limits
|
TWA: 20 CEIL: 30 (ppm) TWA: 70 CEIL: 105 (mg/m3) Consult local authorities for
acceptable exposure limits. |

|
Physical state and appearance |
: |
Liquid. (Oily liquid.) |
|
Odor |
: |
Amine like. (Slight.) |
|
Taste |
: |
Not available. |
|
Molecular Weight |
: |
87.12 g/mole |
|
Color |
|
Clear |
|
pH (1% soln/water) |
: |
Not Available |
|
Boiling Point |
: |
128.19°C (262.7°F) |
|
Melting Point |
: |
-4.9°C (23.2°F) |
|
Critical Temperature |
: |
Not available. |
|
Specific Gravity |
: |
0.9168 (Water = 1) |
|
Vapor Pressure |
: |
7 mm of Hg (@ 20°C) |
|
Vapor Density |
: |
3 (Air = 1) |
|
Volatility |
: |
100% (v/v). |
|
Odor Threshold |
: |
0.1 ppm |
|
Water/Oil Dist. Coeff |
: |
Not available. |
|
Ionicity (in Water) |
: |
Not available. |
|
Dispersion Properties |
: |
See solubility in water. |
|
Solubility |
: |
Easily soluble in cold water. |

|
Stability |
The product is stable. |
|
Instability Temperature |
Not available. |
|
Conditions of Instability |
Not Available. |
|
Incompatibility with various substances |
Not Available. |
|
Corrosivity |
Non-corrosive in presence of glass. |
|
Special Remarks on Reactivity |
Not Available. |
|
Special Remarks on Corrosivity |
Not available. |
|
Polymerization |
No |

|
Routes of Entry
|
Dermal contact. Eye contact. Inhalation. Ingestion
|
|
Toxicity to Animals
|
THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4 HOUR EXPOSURE. Acute oral toxicity (LD50): 525 mg/kg [Mouse]. Acute dermal toxicity (LD50): 500 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 11313.7 ppm 4 hour(s)[Rat].
|
|
Chronic Effects on Humans
|
The substance is toxic to lungs, mucous membranes.
|
|
Other Toxic Effects on Humans
|
Very hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation.
|
|
Special Remarks on Toxicity to Animals
|
Not available.
|
|
Special Remarks on Chronic Effects on Humans
|
Not available.
|
|
Special Remarks on other Toxic Effects on Humans |
Not available. |

ECOTOXICITY EFFECTS:
|
ACUTE TOXICITY: |
None known |
|
MOBILITY: |
NA |
|
PERSISTENCE AND DEGRADABILITY: |
None known
|
|
BIOACCUMULATIVE POTENTIAL: |
Is not known to accumulate |

|
WASTE TREATMENT: |
Dispose of within current local and state regulations.
No special method required. |
|
PACKAGING TREATMENT: |
Consult federal, state, and local regulations regarding the proper disposal of emptied containers. |
|
RCRA HAZARD CLASS: |
NA
|

U.S. DEPARTMENT OF TRANSPORTATION
PROPER SHIPPING
NAME: |
Otherwise Indexed
(NOI)
|
|
HAZARD CLASS: |
Not Regulated
|
|
ID NUMBER: |
NA |
|
LABEL STATEMENT: |
None |
WATER TRANSPORTATION
PROPER SHIPPING
NAME: |
Otherwise Indexed
(NOI) |
|
HAZARD CLASS: |
Not Regulated |
|
ID NUMBER: |
NA |
LABEL
STATEMENT: |
None |
AIR TRANSPORTATION
PROPER SHIPPING
NAME: |
Otherwise Indexed
|
|
HAZARD CLASS: |
Not Regulated |
|
ID NUMBER: |
NA |
|
LABEL |
None |

Preparation does not contain ingredients listed as a dangerous substance in Annex 1 of the EEC directive 67/548.

KEEP OUT OF REACH OF CHILDREN
Although the information and recommendations set forth in this sheet are believed to be correct as of the date hereof, Rx Marine International makes no representation as to the completeness or accuracy of such information and recommendations. Rx Marine International shall in no event be responsible for any damages of whatsoever nature directly or indirectly resulting from the publication or use of or reliance upon such information and recommendations. You are encouraged to advise anyone working with or exposed to such products of the information contained herein.
No Warranty, either expressed or implied, of merchantability or fitness or of any other nature with respect to the product or to the information and recommendations herein made hereunder.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.