|
Product Name |
Peracetic Acid 32% |
|
Part Number |
RXSOL-15-1267-032 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Fujairah. Mumbai, Kandla, Kolkata, Chennai, Visakhapatnam, Muscat, Nairobi
Synonyms : Peroxyacetic acid, Acetyl Hydro peroxide
Molecular formula : C2H4O3 / CH3COOOH
Contains no hazardous ingredients according to GHS.
Classification of the substance or mixture
This product has been classified in accordance with the hazard communication standard 29 CFR 1910.1200; the SDS and labels contain all the information as required by the standard.
Emergency Overview
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Form |
: |
Liquid |
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Physical state |
: |
Liquid |
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Color |
: |
colorless |
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Odor |
: |
pungent |
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OSHA Hazards |
: |
No OSHA Hazards |
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Classification |
: |
Not a hazardous substance or mixture. |
|
Labeling |
: |
Not a hazardous substance or mixture. |
Carcinogenicity:
IARC
No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
NTP
No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
ACGIH
No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
General advice :
If inhaled : Remove from exposure, lie down .Keep warm. Oxygen or artificial respiration if needed.Obtain medical attention
Obtain medical attention
In case of skin contact :Wash off immediately with plenty of water removing all contaminated clothes and shoes.If skin irritation persists, call a physician.
In case of eye contact : Rinse immediately with plenty of water for at least 15 minute and seek medical advice.
If swallowed : Rinse mouth with water .Drink plenty water .Do not induces vomiting .Call a physician immediately
Flash point : 80 oC
Autoignition temperature : 395 oC
Special protective equipment for fire-fighters : Wear a safe contained breathing apparatus, suit protecting against chemicals.
Further information : Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment..
Fire and explosion protection : Water, spray. Do not use dry chemical powder type.
Hazardous decomposition products : Contact with combustible material. May cause fire. Heating >110 oC may cause an explosion.
Environmental precautions : Prevent product from entering drains, into the environment.
Methods for cleaning up : Dam up. Flush very dilute solution into sewer with plenty of water .Contact the proper local authorities. Never return spills in original container of reuse.
Handling
Advice on safe handling : Never return unused material to storage receptacle. Avoid exposure. Provide appropriate exhaust ventilation. Ware suitable protective clothes. Open drum/container carefully .Content may be under pressure.
Advice on protection against fire and explosion : Keep away from sources of ignition .No smoking .Keep away from combustible material. Protect from Contamination .Do not heat over + 30 oC
Storage
Requirements for storage areas and containers : Keep in a cool, well-ventilated plate .keep away from heat, direct sunlight and sources of ignition .Store in original container equipped with a vent. Don’t keep more than 12 months.
Incompatible products : Metal chloride, bases, reducing agents, organic materials, contamination.
Engineering measures
Provide mechanical local exhaust ventilation to prevent release of mist into the work area. If release use respiratory protection.
Exposure limits :
|
ChemicalName |
ACGIH(TLV) |
OSHA(PELs) |
Supplier |
|
Hydrogen Peroxide |
1 ppm (TWA) = 1.4 mg / m3 |
1 ppm (TWA) = 1.4 mg / m3 |
|
|
Acetic Acid |
10 ppm (TWA) = 25 mg / m3
15 ppm (STEL) = 37 mg / m3
|
10 ppm (TWA) = 25 mg / m3 |
|
|
Peracetic Acid |
- |
- |
0.15 ppm (TWA ) = 0.46 mg / m3 |
ACGIH (TLV) = ACGIS & TLV are registered trademarks of The American Conference of Governmental
Industrial Hygienists OSHA (PELs) = Standard of The Occupational Safety and Health Administration
Personal protective equipment
Respiratory protection : In case of insufficient ventilation ware suitable respiratory equipment (filter type B/P3)
Hand protection : Butyl /viton groves. Do not wear leather gloves; do not ware cotton gloves (risk of fire)
Eye protection : Tightly fitting safety goggles and face-shield .Eye wash bottle with pure water.
Skin and body protection : Full protective chemical resistant clothing ,Do not wear leather shoes, Safety shower
Hygiene measures : Avoid exposure.
Gloves Suit
Information on basic physical and chemical properties
Appearance
|
Form |
: |
Liquid |
|
Physical state |
: |
Liquid |
|
Color |
: |
colorless |
|
Odor |
: |
pungent |
|
Flash point |
: |
80 oC |
|
Lower explosion limit |
: |
No data available |
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Upper explosion limit |
: |
No data available |
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Oxidizing properties |
: |
Strong oxidizing |
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Autoignition temperature |
: |
No data available |
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Decomposition temprature |
: |
40 oC SADT ( tank container or tank vehicle max 20 ton ) >/= 65 oC SADT ( IBC max 1.5 m3 ) |
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Molecular formula |
: |
C2H4O3 / CH3COOOH |
|
Molecular weight |
: |
76 |
|
PH |
: |
1 |
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Pour point |
: |
No data available |
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Boiling point/boiling range |
: |
109 oC |
|
Vapor pressure |
: |
22 mm Hg @ 25 oC |
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Relative density |
: |
No data available |
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Water solubility |
: |
completely soluble (100% @ 25 oC) |
|
Partition coefficient: n-octanol/water |
: |
Acetic acid log P ow = -0.17
Peracetic acid log P ow = -0.924
|
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Viscosity, kinematic |
: |
No data available |
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Relative vapor density |
: |
No data available |
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Evaporation rate |
: |
> 1 |
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Percent volatile |
: |
No data available |
Possibility of hazardous reactions
Conditions to avoid : High temperatures. Protect from light .Keep away from heat, contamination.
Materials to avoid : Combustible material, flammable materials, reducing agents, organic material metal chlorides, bases, contamination, rust, dirt.
Thermal decomposition : No data available
Hazardous decomposition products : Heating release irritative and acrid gases.
Acute toxicity :
Peracetic acid : LD 50 / oral/ rat = 652 mg / kg
LD 50 / dermal/rabbit = >200 mg / kg
LC 50 / inhalation / 1 hour/ rat = 590 mg /m3
Ingestion causes burns of the upper digestive tracts and gastrointestinal burns. Inhalation of aerosols may cause irritation to mucous membranes, inflammation, and edema of the lungs
Primary irritation : Causes sever burns.
Sensitisation : no data available
Long term toxicity : no data available
Persistence and degradability : Depending on circumstance, degradable
Bioaccumulation : Does not accumulation
Mobility : no data available
Ecotoxicity effects
Acetic acid : LD 50 / 96hrs. / fathead minnows = 88 mg/l
LD 50 / 96 hrs./ Blugill sunfish = 75 mg/l
LD 50 / 24 hrs. / daphnia = 47 mg/l
Peracetic acid : LD 50 / 96 hrs. / rainbow trout = 10-18 mg/l (12% )
Very toxic to aquatic organism
Hydrogen Peroxide : LD 50 / 96 hrs./ Golden orfe = 35 mg/l
LD 50 / 168 hrs. / fathead minnows = 22-33 mg/l
LD 50 / 96 hrs./ rainbow trout = 38.5 mg/l
EC 50 / daphnia = 2.4-7.7 mg/l
LC 50 / algae > 1.7 mg/l
Contaminated packaging : In accordance with local and national regulations. Rinse empty container with water before disposal .Do not reuse empty container for other purposes.
Waste from residue /unused product : In accordance with local and national regulations, see also accidental release measures. Wear personal protective equipment. Diluted aqueous solution can be disposed as waste water, when in compliance with local regulations. Do not dispose of undiluted solutions into sewer.
The shipping descriptions shown here are for bulk shipments only, and may not apply to shipments in non-bulk packages (see regulatory definition).
Consult the appropriate domestic or international mode-specific and quantity-specific Dangerous Goods Regulations for additional shipping description requirements (e.g., technical name or names, etc.) Therefore, the information shown here, may not always agree with the bill of lading shipping description for the material. Flashpoints for the material may vary slightly between the SDS and the bill of lading.
US DOT (United States Department Of Transportation)
Not regulated as a hazardous material or dangerous goods for transportation by this agency.
IMO / IMDG (International Maritime Dangerous Goods)
Not regulated as a hazardous material or dangerous goods for transportation by this agency.
IATA (International Air Transport Association)
Not regulated as a hazardous material or dangerous goods for transportation by this agency.
ADR (Agreement On Dangerous Goods By Road (Europe))
Not regulated as a hazardous material or dangerous goods for transportation by this agency.
RID (Regulations Concerning The International Transport Of Dangerous Goods (Europe))
Not regulated as a hazardous material or dangerous goods for transportation by this agency.
ADN (European Agreement Concerning The International Carriage Of Dangerous Goods By Inland Waterways)
Not regulated as a hazardous material or dangerous goods for transportation by this agency.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
National legislation
SARA 311/312 Hazards : No SARA Hazards
CERCLA Reportable Quantity : This material does not contain any components with a CERCLA RQ.
SARA 302 Reportable Quantity : This material does not contain any components with a SARA 302 RQ.
SARA 302 Threshold Planning Quantity : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 304 Reportable Quantity : This material does not contain any components with a section 304 EHS RQ.
SARA 313 Ingredients : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Clean Air Act
Ozone-Depletion Potential : This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F).
The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489):
Polypropylene Glycol - 25322-69-4
US State Regulation
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Pennsylvania Right To Know |
: |
No components are subject to the Pennsylvania Right to Know Act. |
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New Jersey Right To Know |
: |
No components are subject to the New Jersey Right to Know Act. |
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California Prop. 65 Ingredients |
: |
This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects.
WARNING! This product contains a chemical known in the State of California to cause cancer.
Propylene oxide |
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Europe REACH |
: |
On the inventory, or in compliance with the inventory |
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United States of America TSCA |
: |
On TSCA Inventory |
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Canada DSL |
: |
All components of this product are on the Canadian DSL. |
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Australia AICS |
: |
On the inventory, or in compliance with the inventory |
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New Zealand NZIoC |
: |
On the inventory, or in compliance with the inventory |
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Japan ENCS |
: |
On the inventory, or in compliance with the inventory |
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Korea KECI |
: |
On the inventory, or in compliance with the inventory |
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Philippines PICCS |
: |
On the inventory, or in compliance with the inventory |
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China IECSC |
: |
On the inventory, or in compliance with the inventory |
NFPA Classification : Health Hazard: 3
Fire Hazard: 1
Stability: 2
Special Precautuion: H
NFPA Ratings Legend :
Severe =4; Serious =3; Moderate =2; Slight =1; Minimal =0
Protection =H (Sefty goggles. gloves, apron, the use of supplied air or SCBA Respirator is Requred in lieu of a vapor cartidge respiroator)
Further information
The information provided in this safety data sheet is correct to the best our knowledge at the data of its publication. The information given is designed only as guidance for safe handing use processing storage, transportation disposal and release and is not to be considered a warranty or quality specification, since the conditions of the operations mentions are beyond our control. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process unless specified in the text .RX Marine International . Disclaims any liability for loss or damage resulting from the use these data ,information or suggestions
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
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