Name: SODIUM HYDROXIDE ANHYDROUS
Brand: Fujairah Chemical
Availability: InStock

Part No: RXSOL-40-1618-050

SODIUM HYDROXIDE ANHYDROUS

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Part No: RXSOL-40-1618-050

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Safety data (MSDS)

Product Name	SODIUM HYDROXIDE ANHYDROUS
Part Number	RXSOL-40-1618-050

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA

Phone	+91 22 20871200 - 1400
Fax	+91 22 27612100 :::AOH :0091 9821214367
Email	mail@rxmarine.com
Website	www.rxmraine.comA

Chemical Name	CAS	EC number	Weight	Formula
Sodium hydroxide	1310-73-2	215-185-5	= 100 %	NaOH

Signal Word	Danger
Hazard Statements	H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage.
Precautionary statements	P234 Keep only in original packaging. P260 Do not breathe dust. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Classification of the substance or mixture	Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008.
Supplemental Hazard Statements	None.
Other hazards	This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

General advice	First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance.
If inhaled	After inhalation: fresh air. Call in physician.
Eye Contact	After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.
Swallowed	After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.
Skin Contact	In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.
Inhalation	Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary.
Ingestion	Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Most important symptoms and effects, both acute and delaye	The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
Indication of any immediate medical attention and special treatment needed	No data available

Flammability	Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Flash Point	Dry powder Dry sand
Suitable extinguishing media	Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media	For this substance/mixture no limitations of extinguishing agents are given.
Special hazards arising from the substance or mixture	Sodium oxides Not combustible. Ambient fire may liberate hazardous vapours.
Further information	Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
Hazardous combustion products	Fire may cause the evolution of Sulphur oxides, nitrogen oxides.
Advice for firefighters	Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Protective Equipment	Use personal protective equipment.
Specific Hazards Arising from the Chemical	Oxides of phosphorus Sodium oxides Not combustible. Fire may cause evolution of: Oxides of phosphorus Ambient fire may liberate hazardous vapours.

Personal precautions, protective equipment and emergency procedures	Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.
Spillage	Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal.
Enviromental Precaution	Do not let product enter drains.
Methods and materials for containment and cleaning	Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts.

Advice on protection against fire and explosion	Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge.
Incompatible materials	Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills.
Hygiene measures	Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2.
Precautions for safe handling	For precautions see section 2.2.
Storage conditions	No metal containers Tightly closed. Dry.
Storage class	Storage class (TRGS 510): 8B: Non-combustible, corrosive hazardous materials
Specific end use(s)	Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
Advice on general occupational hygiene	Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance.
Requirements for storage	Keep in cool and store under shade.

Application Area	Routes of exposure	Health effect	Value
Workers	Inhalation	Long-term local effects	1 mg/m3
Consumers	Inhalation	Long-term local effects	1 mg/m3

Exposure controls	Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Control parameters	Ingredients with workplace control parameters Contains no substances with occupational exposure limit values.
Engineering Control	Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Eye/face protection	Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles
Body Protection	Protective clothing
Skin protection	This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L
Respiratory protection	Required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P2 The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Other Protection Measure	Handle in accordance with good industrial hygiene and safety practice.
Control of environmental exposure	Do not let product enter drains.

Physical state	Pellets
Colour	White
Odour	Odorless
Odor Threshold	No data available
pH	ca.> 14 at 100 g/l at 20 °C
Melting Point	318 °C
Boiling Point	1.390 °C at 1.013 hPa
Flash Point	No data available
Evaporation Rate	Not Applicable
Flammability (solid, gas)	No data available
Explosive limits	No Data Available
Upper/lower flammability or explosive limits	No data available
Autoignition temperature	No data available
Decomposition temperature	No data available
Vapour pressure	No data available
Density	2,13 g/cm3 at 20 °C
Relative Density	No data available
Relative vapor density	1,38 - (Air = 1.0)
Freezing point	No data available
Viscosity	No data available
Partition coefficient	No data available
Explosive properties	No data available
Solubility	1.090 g/l at 20 °C
Ignition temperature	No information available.
Particle characteristics	No data available

Reactivity	No data available
Stability	The product is chemically stable under standard ambient conditions (room temperature) .
Possibility of hazardous reactions	Violent reactions possible with: Acetone Chlorine Ethylene oxide Fluorine Hydrogen halides Hydrazine hydrate hydroxylamine Acid anhydrides Acrolein Acid chlorides Acids sulfuric acid Chloroform Water hydrogen peroxide anhydrides phosphides halogen-halogen compounds trichloroethene can decompose violently in contact with: Organic Substances hydrogen sulphide Risk of ignition or formation of inflammable gases or vapours with: powdered aluminium Ammonium salts persulfates Sodium borohydride phosphorus Oxides of phosphorus Halogenated hydrocarbon Light metals Metals Risk of explosion/exothermic reaction with: Bromine Calcium in powder form furfuryl alcohol Nitromethane Peroxides organic nitro compounds Nitriles Acrylic monomers Chloroform with Acetone Nitrobenzene with Methanol Nitrobenzene with salts magnesium Zinc and Tin (in the presence of atmospheric oxygen and/or moisture)
Conditions to avoid	No data available
Incompatible materials	Aluminum, brass, Metals, metal alloys, Zinc, Tin
Hazardous decomposition products	In the event of fire: see section 5

Acute toxicity	Oral: No data available Symptoms: If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach. Symptoms: burns of mucous membranes, Cough, Shortness of breath, Possible damages:, damage of respiratory tract Dermal: No data available
Skin corrosion/irritation	Skin - Rabbit Result: Causes burns. - 1 h (OECD Test Guideline 404) Remarks: (Regulation (EC) No 1272/2008, Annex VI)
Serious eye damage/eye irritation	Eyes - Rabbit Result: Causes serious eye damage. (OECD Test Guideline 405) Remarks: (Regulation (EC) No 1272/2008, Annex VI) Remarks: Causes serious eye damage.
Respiratory or skin sensitization	Patch test: - In vitro study Result: negative Remarks: (ECHA)
Toxic Effects on Human	May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer).
Carcinogenicity	No data available
Germ cell mutagenicity	No data available
Reproductive toxicity	No data available
Specific target organ toxicity - single exposure	No data available
Endocrine disrupting properties	The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. RTECS: WB4900000 burning sensation, Cough, wheezing, laryngitis, Shortness of breath, spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice.

Bioaccumulative potential	No data available
Persistence and degradability	The methods for determining the biological degradability are not applicable to inorganic substances.
Toxicity to fish	LC50 - Gambusia affinis (Mosquito fish) - 125 mg/l - 96 h Remarks: (ECOTOX Database)
Toxicity to daphnia and other aquatic invertebrates	EC50 - Ceriodaphnia (water flea) - 40,4 mg/l - 48 h Remarks: (ECHA)
Toxicity to algae	IC50 - Desmodesmus subspicatus (green algae) - 46,7 mg/l - 72 h Remarks: (IUCLID) (butyric acid)
Toxicity to bacteria	EC50 - Photobacterium phosphoreum - 22 mg/l - 15 min Remarks: (External MSDS)
Mobility in soil	No Information available
Results of PBT and vPvB assessment	This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting properties	The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Other adverse effects	Harmful effect due to pH shift. Forms corrosive mixtures with water even if diluted. Neutralisation possible in waste water treatment plants. Discharge into the environment must be avoided.

Disposal methods	The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging	Dispose of as unused product.
Waste treatment Method	No data available

UN number	ADR/RID: 1823 IMDG: 1823 IATA: 1823
UN proper shipping name	ADR/RID: Sodium hydroxide, solid IMDG:Sodium hydroxide, solid IATA: Sodium hydroxide, solid
Transport hazard class(es)	ADR/RID: 8 IMDG: 8 IATA: 8
Packaging group	ADR/RID: II IMDG: II IATA: II
Environmental hazards	ADR/RID: NO IMDG: NO IATA: NO
Further information	No data available

Inventory status	Components are on the following inventories: Polymaleic acid: - US TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean, Philippine PICCS and Chinese Xi irritant R 36/38 Irritant to eyes & skin R 41 Risk of serious damage to eyes S24/25 Avoid contact with skin and eyes S26/28 In case of contact eyes & skin, rinse with plenty water and seek medical advice Section 312/313: Not listed. Not listed under California proposition 65.
Safety, health and environmental regulations/legislation specific for the substance or mixture	This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
Other regulations	Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment	A Chemical Safety Assessment has been carried out for this substance.

Other Information

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

SODIUM HYDROXIDE ANHYDROUS

Fujairah Chemical

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