Name: Sodium Meta Bisulphite Food Grade
Brand: Fujairah Chemical
Availability: InStock

Part No: RXSOL-33-6176-050

Sodium metabisulphite used as a disinfectant, antioxidant, and preservative agent.

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Part No: RXSOL-33-6176-050

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Safety data (MSDS)

Porduct Name	Sodium Meta Bisulphite
Part Number	RXSOL-33-6176-050

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA

Phone	+91 22 20871200 - 1400
Fax	+91 22 27612100 :::AOH :0091 9821214367
Email	mail@rxmarine.com
Website	www.rxmraine.com

Chemical Name	Cas No	EC No	Whight	Formula
Sodium Metabisulfite	7681-57-4	231-673-0	190,11 g/mol	Na₂O₅S₂

Hazard Statements	H300 + H310 Fatal if swallowed or in contact with skin.
Precautionary statements	P262 Do not get in eyes, on skin, or on clothing. P280 Wear protective gloves/ protective clothing. P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P302 + P352 + P310 IF ON SKIN: Wash with plenty of water. Immediately call a POISON CENTER/ doctor.
Classification of the substance or mixture	Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008.
Supplemental Hazard Statements	None
Other hazards	This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

General advice	Show this material safety data sheet to the doctor in attendance.
If inhaled	After inhalation: fresh air. Call in physician.
Eye Contact	After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses
Swallowed	After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.
Skin Contact	In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.
Inhalation	Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary.
Ingestion	Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Most important symptoms and effects, both acute and delaye	The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
Indication of any immediate medical attention and special treatment needed	No data available

Flammability	May be combustible at high temperature.
Suitable extinguishing media	Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media	For this substance/mixture no limitations of extinguishing agents are given.
Special hazards arising from the substance or mixture	Sulfur oxides Sodium oxides Not combustible. Ambient fire may liberate hazardous vapours.
Further information	Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
Hazardous combustion products	Fire may cause the evolution of Sulphur oxides, nitrogen oxides.
Advice for firefighters	In the event of fire, wear self-contained breathing apparatus.
Protective Equipment	Use personal protective equipment.
Specific Hazards Arising from the Chemical	Has a fire-promoting effect due to the release of oxygen. Ambient fire may liberate hazardous vapours.

Personal precautions, protective equipment and emergency procedures	Advice for non-emergency personnel: Avoid generation and inhalation of dusts in all circumstances. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.
Personal Protection	Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8.
Enviromental Precaution	Do not let product enter drains.
Methods and materials for containment and cleaning	Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts.
Reference to other sections	For disposal see section 13.

Advice on protection against fire and explosion	Keep away from open flames, hot surfaces and sources of ignition.
Incompatible materials	Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills.
Hygiene measures	Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2.
Advice on safe handling
Conditions for safe storage, including any incompatibilities	Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons. Moisture sensitive.
Storage conditions	Tightly closed. Dry. Do not store near acids. Air and moisture sensitive.
Storage class	Storage class (TRGS 510): 13: Non Combustible Solids
Specific end use(s)	Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
Advice on general occupational hygiene	Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance.

Exposure controls	No specific additional engineering controls are required. Provide good natural or artificial ventilation.
Engineering Control	Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Eye/face protection	Use equipment for eye protection tested and approved under appropriategovernment standards such as NIOSH (US) or EN 166(EU). Safety glasses
Body Protection	protective clothing
Skin protection	This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
Respiratory protection	Recommended Filter type: Filter B-(P3) The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Other Protection Measure	Handle in accordance with good industrial hygiene and safety practice.
Control of environmental exposure	Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Physical state	powder
Colour	colorless
Odour	pungent
Odor Threshold	Not Applicable
pH	4,5 at 50 g/l at 20 °C
Melting Point	> 300 °C
Boiling Point	No data available
Flash Point	No data available
Evaporation Rate	Not Applicable
Flammability (solid, gas)	Flammability (solids)
Explosive limits	No Data Available
Upper/lower flammability or explosive limits	No data available
Autoignition temperature	No data available
Decomposition temperature	No data available
Vapour pressure	No data available
Viscosity	No data available
Density	2,36 g/cm3 at 20 °C
Relative Density	No data available
Specific Gravity	No data available
Partition coefficient	No data available
Explosive properties	No data available
Solubility	650 g/l at 20 °C
Ignition temperature	No information available.
Particle characteristics	No data available

Reactivity	Contact with acids liberates toxic gas.
Chemical stability	The product is chemically stable under standard ambient conditions (room temperature) . Exposure to moisture.
Possibility of hazardous reactions	Generates dangerous gases or fumes in contact with: Acids
Conditions to avoid	Exposure to air. Heat. no information available
Incompatible materials	No information available
Hazardous decomposition products	In the event of fire: see section 5

Acute toxicity	LD50 Oral - Rat - male and female - 1.540 mg/kg (OECD Test Guideline 401) LC50 Inhalation - Rat - male and female - 4 h - > 5,5 mg/l - aerosol (OECD Test Guideline 403) Remarks: (in analogy to similar products)
Skin corrosion/irritation	Skin - Rabbit Result: No skin irritation - 4 h (OECD Test Guideline 404)
Serious eye damage/irritation	Eyes - Rabbit Result: Causes serious eye damage. (OECD Test Guideline 405) Remarks: (Regulation (EC) No 1272/2008, Annex VI)
Respiratory or skin sensitization	Local lymph node assay (LLNA) - Mouse Result: negative (OECD Test Guideline 429)
Carcinogenicity	Presumed to have carcinogenic potential for humans
Germ cell mutagenicity	Test Type: Ames test Test system: Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: Positive results were obtained in some in vitro tests.
Reproductive toxicity	No data available
Specific target organ toxicity - single exposure	No data available
Additional Information	RTECS: UF9625000 Lung irritation, Cyanosis, Central nervous system depression To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Persistence and degradability	The methods for determining the biological degradability are not applicable to inorganic substances
Toxicity to fish	Static test LC50 - Oncorhynchus mykiss (rainbow trout) - 75 mg/l - 96 h (OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrates	static test EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h (OECD Test Guideline 202)
Toxicity	Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 1.520 mg/l - 96 h
Toxicity to bacteria	EC10 - Bacteria - 14 mg/l - 72 h Remarks: (Lit.) EC5 - E.coli - 15.000 mg/l Remarks: (Lit.) (maximum permissible toxic concentration)
Toxicity to algae	Toxicity to algae static test ErC50 - Desmodesmus subspicatus (green algae) - > 100 mg/l - 72 h (OECD Test Guideline 201) static test NOEC - Desmodesmus subspicatus (green algae) - 31,6 mg/l - 72 h (OECD Test Guideline 201)
Products Biodegradation	The methods for determining the biological degradability are not applicable to inorganic substances.
Mobility in soil	No data available
Results of PBT and vPvB assessment	This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting properties	No data available
Other adverse effects	No data available .

Waste treatment Method

No data available

UN number	ADR/RID: IMDG: IATA:
UN proper shipping name	ADR/RID: IMDG: IATA:
Transport hazard class(es)	ADR/RID: IMDG: IATA:
Packaging group	ADR/RID: II IMDG: II IATA:II
Environmental hazards	ADR/RID: No IMDG: No IATA: No
Special precautions for user	No data available
Further information	Not classified as dangerous in the meaning of transport regulations.

Safety, health and environmental regulations/legislation specific for the substance or mixture	This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
Other regulations	Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment	A Chemical Safety Assessment has been carried out for this substance.

Other Information

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.