Acrylic Acid

Acrylic Acid is clear liquid. Acrylic acid participate into a polymer reaction for various uses. Also used in many kinds of copolymers.

SKU: RXSOL-19-1217-050 Category:

Description

Acrylic Acid supplier and Exporter. Acrylic Acid is clear liquid. Acrylic acid participate into a polymer reaction for various uses. Also used in many kinds of copolymers.

Acrylic Acid is a colorless, corrosive organic compound with a sharp, pungent odor. It is an important industrial chemical mainly used in the production of:

  • Acrylic esters

  • Superabsorbent polymers

  • Adhesives

  • Coatings

  • Paints

  • Textiles

  • Water treatment chemicals






Product Details

Application

Acrylic acid used in various application and also as a raw material for acrylic esters in the production of resins for industrial coatings. Acrylic Acid polymer have many application in adhesives, and textiles. Viscosity Modifier; Flocculant; Maintains viscosity.

Dosage & Procedure

Acrylic Acid Glacial is a clear colorless liquid with pungent and non pleasant odor, it can be easily mixed with water, alcohol, ether and Chloroform.
 

Industrial Importance

Acrylic acid is one of the most important raw materials in:

  • Polymer industry

  • Coatings industry

  • Hygiene products manufacturing

Its demand continues to grow due to increasing use in superabsorbent materials and specialty chemicals.

Safety Data (MSDS)

Product Name               Acrylic Acid
Part Number   RXSOL-19-1578-210

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA  

Phone +91 22 20871200 - 1400
Fax +91 22 27612100 :::AOH :0091 9821214367
Email mail@rxmarine.com
Website www.rxmraine.com

Chemical Name                 Cas No                        EC No              Weight                          Formula                   
Acrylic acid  79-10-7 201-177-9 72,06 g/mol C3H4O2
Signal Word  Danger
Hazard Statements H226 Flammable liquid and vapor. H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects. 
Precautionary statements   P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 
Classification of the substance or mixture No data available
Supplemental Hazard    Statements No data available
Other hazards  This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher  

General advice First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance
If inhaled After inhalation fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen
Eye Contact  Rinse out with plenty of water. Remove contact lenses
Swallowed Make victim drink water (two glasses at most). Consult doctor if feeling unwell.
Skin Contact   In case of skin contact Take off immediately all contaminated clothing. Rinse skin with water/ shower.
Inhalation No data available
Ingestion No data available
Most important symptoms and effects,    both acute and delaye The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 
Indication of any immediate medical    attention and special treatment needed  No data available

 Flammability                         No data available
Suitable extinguishing    media  Water Foam Carbon dioxide (CO2) Dry powder
Unsuitable extinguishing    media For this substance/mixture no limitations of extinguishing agents are given
Special hazards arising    from the substance or      mixture  Carbon oxides Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire.
Further information Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
Hazardous combustion
products
No data available
Advice for firefighters Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing
Protective Equipment No data available
Specific Hazards Arising      from the  Chemical No data available

Personal precautions,    protective equipment and    emergency procedures Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.
Spillage No data available
Personal Protection Avoid dust formation. Avoid breathing vapors, mist or gas. For personal protection see section 8 
Enviromental Precaution Do not let product enter drains. Risk of explosion.
Methods and materials for
containment and cleaning
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area
Reference to other          sections    For disposal see section 13

Advice on protection    against  fire and explosion  Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. 
Incompatible materials  No data available
Hygiene measures Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2.
Advice on  safe handling Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.
Conditions for safe          storage, including any      incompatibilities 

No data available

Storage conditions Adhere to recommended storage temperature. Crystallises at approx. +13°C. Do not store below +15°C. Risk of explosion. Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Recommended storage temperature see product label. 
Storage class Storage class (TRGS 510) 3 Flammable liquids
Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
Advice on general      occupational  hygiene No data available

Exposure controls  Personal protective equipment 
Engineering Control No data available
Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Body Protection Flame retardant antistatic protective clothing.
Skin protection This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Viton® Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M) This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: butyl-rubber Minimum layer thickness: 0,7 mm Break through time: 30 min Material tested:Butoject® (KCL 898)
Respiratory protection
Recommended Filter type Filter A-(P2) The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Other Protection  Measure No data available

Physical state Liquid
Colour Colorless
Odour No data available
Odor Threshold No data available
pH No data available
Melting Point 13 °C
Boiling Point 141 °C at 1.013 hPa
Flash Point 48,5 °C - closed cup - DIN 51755 Part 1
Evaporation Rate No data available
Flammability (solid, gas) No data available
Explosive limits No data available
Upper/lower flammability or explosive limits No data available
Autoignition temperature 438 °C at 1.013 hPa
Decomposition temperature  No data available
Vapour pressure 5,29 hPa at 25 °C
Viscosity Dynamic 1,15 mPa.s at 25 °C
Density 1,05 g/cm3 at 20 °C
Relative Density 1,05 at 20 °C 
Specific Gravity No data available 
Partition coefficient log Pow 0,46 at 25 °C - Bioaccumulation is not expected
Explosive properties No data available 
Solubility 1.000 g/l at 25 °C  
Ignition temperature No data available 
Particle characteristics No data available 

Reactivity                        Vapor/air-mixtures are explosive at intense warming.
Chemical stability Prolonged storage of the product can cause the stabilizer to lose its effectiveness. The product is chemically stable under standard ambient conditions (room temperature) . Contains the following stabilizer(s): hydroquinone monomethyl ether (0,02 %)
Possibilityof hazardous      reactions Risk of explosion with  Oxidizing agents polymerisation initiators Peroxides Oxygen Violent polymerization may be caused by alkali hydroxides Amines Ammonia sulfuric acid mercaptans azides Ether Ketones Aldehydes nitrates nitrites increased reactivity with: anhydrides
Conditions to avoid Avoid temperatures below recommended storage temperature. Heating.                                                                           
Incompatible materials
Copper, Nickel, Mild steel, Zinc
Hazardous product        dicomposition                                                         No data available

Acute toxicity  Acute toxicity estimate Oral - 500,1 mg/kg (Calculation method) LD50 Oral - Rat - male - 1.000 - < 2.000 mg/kg (OECD Test Guideline 423)  Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) Symptoms: If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach. Acute toxicity estimate Inhalation - 4 h - 11 mg/l - vapor(Calculation method) LC50 Inhalation - Rat - 4 h - 3,6 mg/l - vapor  (Lit.) (Regulation (EC) No 1272/2008, Annex VI) Symptoms: mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of respiratory tract Acute toxicity estimate Dermal - 1.101 mg/kg (Calculation method) LD50 Dermal - Rabbit - male - 1.000 mg/kg (Regulation (EC) No 1272/2008, Annex VI)
Skin corrosion/irritation Skin - Rabbit Result Causes severe burns. (OECD Test Guideline 404) (Regulation (EC) No 1272/2008, Annex VI)
Serious eye      damage/irritation Eyes - Rabbit Result: Causes burns.  (IUCLID) Causes serious eye damage.
Respiratory or skin  sensitization  Sensitisation test - Guinea pig Result negative  (Lit.) 
Carcinogenicity No data available
Germ  cell            mutagenicity  Test Type Ames test Test system: Salmonella typhimurium Result: negative (National Toxicology Program) Test Type: In vitro mammalian cell gene mutation test Test system: Chinese hamster ovary cells Metabolic activation with and without metabolic activation Method OECD Test Guideline 476 Result negative Test Type unscheduled DNA synthesis assay Millipore- 8.00181 Page 9 of 12 The life science business of Merck operates as MilliporeSigma in the US and Canada Test system: rat hepatocytes Metabolic activation without metabolic activation Method OECD Test Guideline 482 Result negative Test Type Mutagenicity (mammal cell test) chromosome aberration. Species Rat Cell type: Bone marrow Application Route Oral Method OECD Test Guideline 475 Result negative Test Type dominant lethal test Species: Mouse Cell type Intrauterine Application Route Oral Result negative  (ECHA)
Reproductive toxicity  No data available
Specific target    organ toxicity-      single exposure
No data available
Additional Information Assessment The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Repeated dose toxicity - Rat - male - Oral - NOAEL (No observed adverse effect level) - 40 mg/kg - LOAEL (Lowest observed adverse effect level) - 100 mg/kg burning sensation, Cough, wheezing, laryngitis, Shortness of breath, spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice. Millipore- 8.00181 Page 10 of 12 The life science business of Merck operates as MilliporeSigma in the US and Canada Liver - Irregularities - Based on Human Evidence 

Persistence and      degradability Biodegradability Result 100 % - Readily eliminated from water (OECD Test Guideline 302B) Result 81 % - Readily biodegradable. (OECD Test Guideline 301D) 
Toxicity to fish  Flow-through test LC50 - Oncorhynchus mykiss (rainbow trout) - 27 mg/l - 96 h (US-EPA)
Toxicity to daphnia and other aquatic      invertebrates Flow-through test EC50 - Daphnia magna (Water flea) - 95 mg/l - 48 h (US-EPA)
Toxicity No data available
Toxicity to bacteria   No data available
Toxicity to algae IC50 - Desmodesmus subspicatus (green algae) - 0,13 mg/l - 72 h (Regulation (EC) No. 440/2008, Annex, C.3)  (IUCLID) EC10 - Desmodesmus subspicatus (green algae) - 0,03 mg/l - 72 h (Regulation (EC) No. 440/2008, Annex, C.3) (ECHA)
Mobility in soil No data available
Results of PBT av PvB  assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting      properties The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Other adverse effects Biological effects Neutralise before sewage disposal. Discharge into the environment must be avoided.

Product See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. 
Contaminated packaging No data available
Waste treatment    Method No data available

UN number

ADR/RID:2218                            IMDG:2218                                            IATA:2218

UN proper shipping      name  ADR/RID:ACRYLIC ACID, STABILIZED          IMDG:ACRYLIC ACID,STABILIZED          IATA:ACRYLIC ACID, STABILIZED 
Transport hazard      classess     ADR/RID:8 (3)                               IMDG:8 (3)                                           IATA:8 (3) 
Packaging group ADR/RID:ll                                     IMDG:ll                                                 IATA:ll
Environmental hazards ADR/RID:Yes                                IMDG Marine pollutant: Yes                  IATA: No
Special precautions for    user No data available
Further information No data available

Safety, health and environmental    regulations/legislation specific for the      substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
Other regulations Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment For this product a chemical safety assessment was not carried out

Other Information

The information above is believed to be accurate and represents the  best information   currently    available  to us.  However,   we   make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and  weassume  no liability resulting from its use. Users should make  their  own  investigations  to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International  has been advised of the possibility of such damages.

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