It contains an aluminium trichloride
Aluminium trichloride hexahydrate is a hydrate It contains an aluminium trichloride A compound with the chemical formula AlCl3 the anhydrous salt is used as a catalyst in organic chemical synthesis and hydrated salts are used topically as antiperspirants and for the management of HYPERHYDROSIS.
Aluminum chloride is used widely in manufacturing rubber, lubricants, wood preservatives, and paints. It is used in pesticides and pharmaceuticals.
It reacts violently with water and is highly corrosive, requiring careful handling
CAS No. 7446-70-0.
Molecular Formula, AlCl3,
Molecular Weight, 133.34.
H.S. Code, 2827.3200,
Shelf Life, 60 Months.
| Product Name | Aluminium Chloride Hexahydrate |
| Part Number | RXSOL-19-4097-200 |
Company Details:....
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| mail@rxmarine.com | |
| Website | www.rxmraine.com |
Substances
| Synonyms | Aluminium chloride |
| Formula | AlCl3 · 6H2O |
| Molecular weight | 241,43 g/mol |
| CAS-No. | 7784-13-6 |
| EC-No. | 231-208-1 |
| Index-No. | 013-003-00-7 |
| Component | Classification | Concentration |
| aluminum chloride hexahydrate | ||
|
CAS-No. 7784-13-6
EC-No 231-208-1
Index-No. 013-003-00-7
|
Skin Corr. 1B; Eye Dam.
1; H314, H318
|
<= 100 % |
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification of the substance or mixture
| Classification according to Regulation (EC) No 1272/2008 |
Skin corrosion (Sub-category 1B), H314
Serious eye damage (Category 1), H318
For the full text of the H-Statements mentioned in this Section, see Section 16.
|
Label elements
| Signal word | Danger |
|
Hazard Statements |
H314 Causes severe skin burns and eye damage. |
|
Precautionary Statements |
P260 Do not breathe dust.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P363 Wash contaminated clothing before reuse.
|
| Supplemental Hazard Statements | None |
| Other hazards |
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
Ecological information:
The substance/mixture does not contain components considered to have endocrine
disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Toxicological information:
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
|
Description of first aid measures
| General advice | First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance. |
| If inhaled | After inhalation: fresh air. Call in physician. |
| In case of skin contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately. |
| In case of eye contact | Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. |
| If swallowed | Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. |
| Most important symptoms and effects, both acute and delayed | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
Extinguishing media
| Suitable extinguishing media | Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. |
| Special hazards arising from the substance or mixture |
Nature of decomposition products not known.
Hydrogen chloride gas
Aluminum oxide
Not combustible.
Ambient fire may liberate hazardous vapours.
|
| Advice for firefighters |
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact bykeeping a safe distance or by wearing suitable protective clothing.
|
| Further information | Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
| Personal precautions, protective equipment and emergency procedures |
Wear respiratory protection. Avoid dust formation. Avoid breathing vapors, mist or gas.
Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
|
| Environmental precautions |
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Discharge into the environment must be avoided.
|
| Methods and materials for containment and cleaning up | Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. |
| Reference to other sections | For disposal see section 13. |
| Precautions for safe handling | For precautions see section 2.2. |
| Conditions for safe storage, including any incompatibilities | |
| Storage conditions |
Tightly closed. Dry.
Caution: the anhydrous form of this material has been reported to have the following
hazards associated with it. Prolonged storage of anhydrous aluminum chloride in closed
containers has resulted in spontaneous decomposition and occasional explosion upon
opening the container probably due to the diffusion of moisture into the container with
resulting pressure build-up due to liberated hydrogen chloride gas. When heated in a
sealed tube, high internal pressure may be generated due to not only its vapor pressure
and pressure of desorbed hydrogen chloride, but also by the near doubling in volume which occurs when the material melts to the monomer. Mixtures of nitrobenzene and aluminum chloride are thermally unstable and may lead to explosive decomposition due to a multistep decomposition reaction occurring above 90°C, which self-accelerates with high exothermicity producing azo- and azoxypolymers. Violent exothermic reactions can occur upon aluminum chloride contacting: alkenes, a mixture of benzoyl chloride and naphthalene, a mixture of aniline and ethyleneimine, ethylene oxide, a mixture of sodium peroxide and aluminum. Aluminum chloride reacts explosively with: oxygen difluoride, phenyl azide, perchloryl benzene or sodium borohydride.
Moisture sensitive.
|
| Storage class | Storage class (TRGS 510): 8B: Non-combustible, corrosive hazardous materials |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
Control parameters
Ingredients with workplace control parameters
Exposure controls
Personal protective equipment
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles |
| Skin protection |
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN 16523-1 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Full contact
Material: Chloroprene
Minimum layer thickness: 0,65 mm
Break through time: 480 min
Material tested:KCL 720 Camapren®
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN 16523-1 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: Latex gloves
Minimum layer thickness: 0,6 mm
Break through time: 60 min
Material tested:Lapren® (KCL 706 / Aldrich Z677558, Size M). |
| Body Protection | Acid-resistant protective clothing |
| Respiratory protection |
Recommended Filter type: Filter A-(P3)
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory
protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
|
| Control of environmental exposure | Do not let product enter drains. |
| Physical state | Crystalline |
| Colour | Colorless |
| Odor | Odorless |
| Melting point/freezing point | Melting point/range: 100 °C |
| Initial boiling point and boiling range | No data available |
| Flammability (solid, gas) | The product is not flammable. |
| Upper/lower flammability or explosive limits | No data available |
| Flash point | Not applicable |
| Autoignition temperature | No data available |
| Decomposition temperature | No data available |
| pH | ca.2,5 at 50 g/l at 20 °C |
| Viscosity |
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
|
| Water solubility | 1.330 g/l at 20 °C |
| Partition coefficient: n-octanol/water | Not applicable for inorganic substances |
| Vapor pressure | 1,3332 hPa at 100 °C |
| Density | 2,398 g/cm3 at 20 °C |
| Relative density | No data available |
| Relative vapor density | No data available |
| Particle characteristics | No data available |
| Explosive properties | No data available |
| Oxidizing properties | None |
| Other safety information | No data available |
| Reactivity | No data available |
| Chemical stability |
The product is chemically stable under standard ambient conditions (room temperature) .
May decompose on exposure to moist air or water.
|
| Possibility of hazardous reactions | No data available |
| Conditions to avoid | Avoid moisture. |
| Incompatible materials |
Metals
|
| Hazardous decomposition products | In the event of fire: see section 5 |
Information on toxicological effects
| Acute toxicity |
LD50 Oral - Rat - 3.311 mg/kg
Remarks: (RTECS)
Symptoms: If ingested, severe burns of the mouth and throat, as well as a danger of
perforation of the esophagus and the stomach., Nausea, Vomiting
Symptoms: mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of
respiratory tract
LD50 Dermal - Rabbit - > 2.000 mg/kg
Remarks: (RTECS)
(anhydrous substance)
The value is given in analogy to the following substances: aluminium(III) chloride,
anhydrous
|
| Skin corrosion/irritation |
Skin - In vitro study
Result: Corrosive
(OECD Test Guideline 435)
Remarks: The value is given in analogy to the following substances: aluminium(III)
chloride, anhydrous
|
| Serious eye damage/eye irritation | Remarks: Causes serious eye damage. |
| Respiratory or skin sensitization |
Sensitisation test: - Guinea pig
Result: negative
(OECD Test Guideline 406)
Remarks: The value is given in analogy to the following substances: aluminium(III)
chloride, anhydrous
|
| Germ cell mutagenicity |
Test Type: Mammal
Test system: lymphocyte
Remarks: DNA damage
|
| Carcinogenicity | No data available |
| Reproductive toxicity |
No data available
|
| Specific target organ toxicity (single exposure) | No data available |
| Specific target organ toxicity (repeated exposure) | No data available |
| Aspiration hazard | No data available |
| Additional Information | |
|
Endocrine disrupting properties
Product
|
|
| Assessment |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
RTECS: BD0530000 Cough, Shortness of breath, Headache, Nausea, Vomiting
To the best of our knowledge, the chemical, physical, and toxicological properties have not
been thoroughly investigated.
The following applies to aluminium compounds in general: After swallowing: only slightly
absorbable via the gastrointestinal tract. Serious disorders in man (from about 4000 mg
aluminium up): phosphate metabolism, calcium metabolism.
Other dangerous properties can not be excluded.
Handle in accordance with good industrial hygiene and safety practice.
|
| Toxicity |
Toxicity to daphnia Remarks: No data available
and other aquatic (Sodium hydrosulfide hydrate)
invertebrates
|
| Persistence and degradability | No data available |
| Bioaccumulative potential | No data available |
| Mobility in soil | No data available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | No data available |
| Other adverse effects |
Very toxic to aquatic life.
No data available
|
| Waste treatment Method | |
| Product | Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself. |
| Contaminated packaging | Dispose of as unused product. |
| UN number | ADR/RID:3260 IMDG:3260 IATA: 3260 |
| UN proper shipping name |
ADR/RID: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (aluminum chloride
hexahydrate)
IMDG: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (aluminum chloride
hexahydrate)
IATA: Corrosive solid, acidic, inorganic, n.o.s. (aluminum chloride hexahydrate)
|
| Transport hazard class(es) | ADR/RID: 8 IMDG: 8 IATA:8 |
| Packaging group | ADR/RID: II IMDG: II IATA:II |
| Environmental hazards | ADR/RID: no IMDG Marine pollutant: no IATA: no |
| Special precautions for user | No data available |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Other regulations | Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | For this product a chemical safety assessment was not carried out |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
