TETRAHYDROFURAN
TETRAHYDROFURAN
Product Details
Safety Data (MSDS)
| Product Name | TETRAHYDROFURAN |
| Part Number | RXSOL-19-6605-689 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| mail@rxmarine.com | |
| Website | www.rxmraine.com |
| Chemical Name | CAS No | EC number | Weight | Formula |
| Tetrahydrofuran for analysis | 109-99-9 | 5-53 | 72,11 g/mol | C4H8O |
| Signal Word | Danger |
| Hazard Statements | H225 Highly flammable liquid and vapor. H302 Harmful if swallowed. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer.5 |
| Precautionary statements | P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. |
| Classification of the substance or mixture | No data available |
| Supplemental Hazard Statements | No data avaialble |
| Other hazards | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| General advice | Show this material safety data sheet to the doctor in attendance. |
| If inhaled | After inhalation fresh air. Call in physician. |
| Eye Contact | Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. |
| Swallowed | After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. |
| Skin Contact | In case of skin contact Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician. |
| Inhalation | No data available |
| Ingestion | No data available |
| Most important symptoms and effects, both acute and delaye | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Flammability | May be combustible at high temperature. |
| Suitable extinguishing media | Carbon dioxide (CO2) Foam Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given |
| Special hazards arising from the substance or mixture | Carbon oxides Combustible. Pay attention to flashback. Vapors are heavier than air and may spread along floors. Development of hazardous combustion gases or vapours possible in the event of fire. Forms explosive mixtures with air at ambient temperatures. |
| Further information | Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
|
Hazardous combustion products |
No data available |
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Protective Equipment | Use personal protective equipment. |
| Specific Hazards Arising from the Chemical | No data available |
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
| Spillage | No data available |
| Personal Protection | No data available |
| Enviromental Precaution | Do not let product enter drains. Risk of explosion. |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area. |
| Advice on safe handling | Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols |
| Advice on protection against fire and explosion | Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
| Incompatible materials | No data available |
| Hygiene measures | Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
| Conditions for safe storage, including any incompatibilities | No data available |
| Storage conditions | Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Protected from light.Keep container tightly closed in a dry and wellventilated place. Keep away from heat and sources of ignition. Recommended storage temperature see product label. |
| Storage class | Storage class (TRGS 510) 3 Flammable liquids |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Advice on general occupational hygiene | No data available |
| Exposure controls | Personal protective equipment |
| Engineering Control | No data available |
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
| Body Protection | Flame retardant antistatic protective clothing |
| Skin protection | This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: butyl-rubber Minimum layer thickness: 0,7 mm Break through time: 10 min Material tested:Butoject® (KCL 898) |
| Respiratory protection | Recommended Filter type Filter A (acc. to DIN 3181) for vapours of organic compounds The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. |
| Control of environmental exposure | Do not let product enter drains. Risk of explosion. |
| Physical state | Liquid |
| Colour | Colorless |
| Odour | No data available |
| Odor Threshold | Not Applicable |
| pH | ca.7 - 8 |
| Melting Point | -108,44 °C - (ECHA) |
| Boiling Point | 65 °C at 1.013,25 hPa - (ECHA) |
| Flash Point | -21,2 °C - closed cup - DIN 51755 Part 1 |
| Evaporation Rate | No data available |
| Flammability (solid, gas) | No data available |
| Explosive limits | No data available |
| Upper/lower flammability or explosive limits | Upper explosion limit12,4 %(V) - (THF) Lower explosion limit 1,5 %(V) |
| Autoignition temperature | 215 °C at 1.013 hPa - DIN 51794 |
| Decomposition temperature | No data available |
| Viscosity | Dynamic 0,359 mPa.s at 50 °C0,456 mPa.s at 25 °C |
| Vapour pressure | 170 hPa at 20 °C - (THF) |
| Density | 0,89 g/cm3 at 20 °C |
| Relative Vapour Density | No data available |
| Freezing point | No data available |
| Specific Gravity | No data available |
| Partition coefficient | Log Pow 0,45 at 25 °C - Bioaccumulation is not expected. |
| Explosive properties | No data available |
| Solubility | ca.0,089 g/l at 25 °C |
| Ignition temperature | No information available. |
| Particle characteristics | No data available |
| Reactivity | Formation of peroxides possible. Vapors may form explosive mixture with air. |
| Stability | Sensitivity to lightSensitive to air. The product is chemically stable under standard ambient conditions (room temperature) . Contains the following stabilizer(s): butyl hydroxytoluene (BHT) (<0,0250,0249 %) |
| Possibility of hazardous reactions | A risk of explosion and/or of toxic gas formation exists with the following substances alkali hydroxides Bromine hydrides Potassium lithium aluminium hydride thionyl chloride Oxidizing agents Oxygen aminophenol with Peroxides Exothermic reaction with: Acids halides peroxi compounds |
| Conditions to avoid | Distillation (Risk of explosion). Warming. Moisture. |
| Incompatible materials | No data available |
| Hazardous Polymerization | Peroxides In the event of fire see section 5 |
| Acute toxicity | Acute toxicity estimate Oral - 1.651 mg/kg (Calculation method) LD50 Oral - Rat - male and female - 1.650 mg/kg Remarks: (ECHA) Symptoms: Irritation of mucous membranes Acute toxicity estimate Oral - 1.650 mg/kg (ATE value derived from LD50/LC50 value) LC50 Inhalation - Rat - male and female - 6 h - > 14,7 mg/l - vaporUS-EPA) LD50 Dermal - Rat - male and female - > 2.000 mg/kg (OECD Test Guideline 402 |
| Skin corrosion/irritation | Skin - Rabbit - 72 h (Draize Test) Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing properties of the product. |
| Serious eye damage/eye irritation | Eyes - Rabbit Causes serious eye irritation. (IUCLID) Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) |
| Respiratory or skin sensitization | Local lymph node assay (LLNA) - Mouse negative (OECD Test Guideline 429) |
| Carcinogenicity | Suspected of causing cancer. |
| Germ cell mutagenicity | Test Type Ames test Test system: S. typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Test Type: In vitro mammalian cell gene mutation test Test system: Chinese hamster ovary cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: negative Test Type: Chromosome aberration test in vitro Test system: Chinese hamster ovary cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 473 Result: negative Test Type: Micronucleus test Species: Mouse Cell type: Red blood cells (erythrocytes) Application Route: inhalation (vapor) Method: OECD Test Guideline 474 |
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure | Inhalation - May cause respiratory irritation. - Central nervous system Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)May cause drowsiness or dizziness. |
| Additional Information | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Repeated dose toxicity - Rat - male and female - Oral - 4 Weeks irritant effects, Cough, Shortness of breath, narcosis, somnolence To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. In high doses: somnolence narcosis Other dangerous properties can not be excluded. This substance should be handled with particular care. |
| Persistence and degradability | Biodegradability aerobic Biochemical oxygen demand - Exposure time 28 dResult: 39 % - Not readily biodegradable. (OECD Test Guideline 301D) |
| Toxicity to fish | Flow-through test LC50 - Pimephales promelas (fathead minnow) - 2.160 mg/l - 96 h (OECD Test Guideline 203) |
| Toxicity to daphnia and other aquatic invertebrates | Static test EC50 - Daphnia magna (Water flea) - 3.485 mg/l - 48 h (OECD Test Guideline 202) |
| Toxicity to algae | No data available |
| Toxicity to bacteria | No data available |
| Mobility in soil | No data available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Other adverse effects | No data available |
| Disposal methods | No data available |
| Contaminated packaging | No data available |
| Waste treatment Method | No data available |
| UN number | ADR/RID:2056 | IMDG:2056 | IATA:2056 |
| UN proper shipping name | ADR/RID:TETRAHYDROFURAN | IMDG:TETRAHYDROFURAN | IATA:TETRAHYDROFURAN |
| Transport hazard class(es) | ADR/RID:3 | IMDG:3 | IATA:3 |
| Packaging group | ADR/RID:ll | IMDG:ll | IATA:ll |
| Environmental hazards | ADR/RID:No | IMDG:No | IATA:No |
| Special precautions for user | Tunnel restriction code (D/E) | ||
| Further information | No data available |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Other regulations | Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | For this product a chemical safety assessment has been carried out. |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
