Trimethylhydroquinone

Trimethylhydroquinone Is hydroquinone substituted by methyl groups at positions 2 3 and 5 ::: NOT FOR SALE

SKU: RXSOL-19-9507-025 Category:

Description

2 3 5 trimethylhydroquinone is a member of the class of hydroquinones that is hydroquinone substituted by methyl groups at positions 2 3 and 5 It is a member of hydroquinones and a methylbenzene.






Product Details

Application

Trimethylhydroquinone (2,3,5-trimethylhydroquinone or TMHQ) is a key organic chemical compound with the molecular formula C₉H₁₂O₂, primarily used as an essential intermediate for synthesizing vitamin E, antioxidants, and dyes.

Dosage & Procedure

Used as a medicine, feed, food, cosmetic additives, industrial antioxidants, polyolefin non-toxic, biodegradable stabilizer.

Safety Data (MSDS)

Porduct Name               Trimethylhydroquinone 
Part Number   RXSOL-19-9507-025

Company Details:....

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA  

Phone +91 22 20871200 - 1400
Fax +91 22 27612100 :::AOH :0091 9821214367
Email mail@rxmarine.com
Website www.rxmraine.com

Chemical Name                 Cas No                        EC No              Whight                          Formula                   
Trimethylhydroquinone         700-13-0 211-838-3 152,19 g/mol C9H12O2
Component                                              Classification                         Concentration                                           
2,3,5-Trimethylhydroquinone                                                                                                                                   
CAS-No.    700-13-0
EC-No.      211-838-3
Index-No.  604-045-00-2 
 
              
Acute Tox. 4; Skin Irrit. 2;
Eye Dam. 1; Skin Sens. 1;
STOT SE 3; Aquatic Acute
1; Aquatic Chronic 1;
H332, H315, H318, H317,
H335, H400, H410        
<= 100 %                                                                            
 

For the full text of the H-Statements mentioned in this Section, see Section 16.

 
Classification of the substance or mixture
 
Classification according to Regulation (EC) No 1272/2008 
Acute toxicity, Inhalation (Category 4), H332
Skin irritation (Category 2), H315
Serious eye damage (Category 1), H318
Skin sensitization (Category 1), H317
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
Short-term (acute) aquatic hazard (Category 1), H400
Long-term (chronic) aquatic hazard (Category 1), H410 
For the full text of the H-Statements mentioned in this Section, see Section 16
 
Labelling according Regulation (EC) No 1272/2008
 
Signal Word Danger
Hazard statement(s)  
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/ eye protection/ face protection.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER/ doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
Supplemental Hazard Statements None

Reduced Labeling (<= 125 ml)

Signal Word Danger
Hazard statement(s)  
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
Precautionary statement(s)
P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P280 Wear protective gloves/ eye protection/ face protection.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
Supplemental Hazard Statements None
Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

General advice Show this material safety data sheet to the doctor in attendance.
If inhaled After inhalation: fresh air.
In case of skin contact In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.
In case of eye contact After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses. 
If swallowed After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.
Most important symptoms and effects, both acute and delaye The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
Indication of any immediate medical attention and special treatment needed  No data available

Suitable extinguishing media  Water Foam Carbon dioxide (CO2) Dry powder
Unsuitable extinguishing media For this substance/mixture no limitations of extinguishing agents are given.
Special hazards arising from the substance or mixture 
Carbon oxides
Combustible.
Vapors are heavier than air and may spread along floors.
Forms explosive mixtures with air on intense heating.
Development of hazardous combustion gases or vapours possible in the event of fire.
Advice for firefighters Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. 
Prevent fire extinguishing water from contaminating surface water or the ground water system. Prevent fire extinguishing water from contaminating surface water or the ground water system.

Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.
Enviromental Precaution Do not let product enter drains.
Methods and materials for
containment and cleaning up 
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts.
Reference to other sections    For disposal see section 13.

Advice on    safe handling Work under hood. Do not inhale substance/mixture. 
Hygiene measures Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. 
Storage conditions Tightly closed. Dry.
Storage class Storage class (TRGS 510): 11: Combustible Solids
Specific end     use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

Control parameters
Ingredients with workplace control parameters
Exposure controls
Personal protective equipment
Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles
Skin protection
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Material tested :KCL 741 Dermatril® L
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Material tested: KCL 741 Der matril  L
Body Protection Protective clothing
Respiratory protection
Required when dusts are generated.
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
Recommended Filter type: Filter type P2
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
Control of    environmental exposure Do not let product enter drains.

Physical state Powder
Colour Beige
Odour No data available
Melting point/freezing point Melting point/range: 169 - 172 °C - lit.
Initial boiling point and boiling range 293 - 298 °C at 1.013 hPa - OECD Test Guideline 103
Flammability (solid, gas) No data available
Upper/lower flammability or explosive limits No data available
Flash point 191 °C - closed cup
Autoignition temperature No Data Available
Decomposition temperature No data available
pH No data available
Viscosity
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
Water solubility 0,9 g/l at 20 °C - OECD Test Guideline 105                                             
Partition coefficient: n-octanol/water Not applicable for inorganic substances   
Vapor pressure No data available
Density No data available
Relative Density No data available
Relative vapor density No data available 
Particle characteristics No data available
Explosive properties No data available 
Oxidizing properties None
Other safety information  
Solubility in other solvents Methanol 100 g/l - soluble

Reactivity                       
Forms explosive mixtures with air on intense heating.
A range from approx. 15 Kelvin below the flash point is to be rated as critical.
The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.
Chemical stability The product is chemically stable under standard ambient conditions (room temperature)
Possibility of hazardous reactions No data available
Conditions to avoid Strong heating.                                                                                     
Incompatible materials
Oxidizing agents
Hazardous decomposition products In the event of fire: see section 5

Acute toxicity 
LD50 Oral - Rat - male - 3.200 mg/kg
(OECD Test Guideline 401)
Remarks: Lungs, Thorax, or Respiration:Other changes.
LC50 Inhalation - Rat - 4 h - 1.500 mg/m3 - dust/mist
Remarks: Sense Organs and Special Senses (Nose, Eye, Ear, and Taste):Eye:Corneal
damage.
Cardiac:Other changes.
Lungs, Thorax, or Respiration:Emphysema.
LD50 Dermal - Rabbit - > 200 mg/kg                    
Skin corrosion/irritation
Skin - Rabbit
Result: Skin irritation
(OECD Test Guideline 404)
Serious eye      damage/irritation
Eyes - Rabbit
Result: Risk of serious damage to eyes.
(OECD Test Guideline 405)
Respiratory or skin    sensitization 
In vivo assay - Guinea pig
Result: positive
Remarks: (ECHA)
Germ cell mutagenicity 
Test Type: Ames test
Test system: S. typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
Carcinogenicity No data available
Reproductive toxicity  No data available
Specific target organ toxicity - single      exposure Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure No data available
Aspiration hazard No data available
Additional Information  
Endocrine disrupting properties 
Product
 
Assessment
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
RTECS: MX7820000
To the best of our knowledge, the chemical, physical, and toxicological properties have not
been thoroughly investigated.

Toxicity No data available
Toxicity to daphnia
and other aquatic
invertebrates
Static test EC50 - Daphnia magna (Water flea) - 1,1 mg/l - 48 h (OECD Test Guideline 202)
Toxicity to algae Static test EC50 - Desmodesmus subspicatus (green algae) - 13 mg/l - 72 h (DIN 38412)
Persistence and degradability Biodegradability aerobic - Exposure time 28 d (OECD Test Guideline 301A)
Bioaccumulative potential No data available
Mobility in soil No data available
Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting       properties  
Assessment The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Other adverse effects No data available .

Waste treatment Method         No data available              

UN number ADR/RID:3077                IMDG:3077          IATA: 3077
UN proper shipping name 
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2,3,5-
Trimethylhydroquinone) (2,3,5-Trimethylhydroquinone)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2,3,5-
Trimethylhydroquinone) (2,3,5-Trimethylhydroquinone)
IATA: Environmentally hazardous substance, solid, n.o.s. (2,3,5-
Trimethylhydroquinone) (2,3,5-Trimethylhydroquinone) 
Transport hazard class(es)      ADR/RID: 9              IMDG: 9               IATA:9
Packaging group ADR/RID: IIl                 IMDG:     IlI      IATA:IIl
Environmental hazards ADR/RID: yes          IMDG Marine pollutant: yes         IATA: yes
Special precautions for user Tunnel restriction code : (-)
Further information EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.Packages smaller than or equal to 5 kg / L , not dangerous goods of Class 9

Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
Other regulations Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment For this product a chemical safety assessment was not carried out

Other Information

The information above is believed to be accurate and represents the  best information   currently    available  to us.  However,   we   make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and  weassume  no liability resulting from its use. Users should make  their  own  investigations  to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International  has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

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