Acrylic Acid is clear liquid. Acrylic acid participate into a polymer reaction for various uses. Also used in many kinds of copolymers.
Acrylic Acid supplier and Exporter. Acrylic Acid is clear liquid. Acrylic acid participate into a polymer reaction for various uses. Also used in many kinds of copolymers. Acrylic Acid is a colorless, corrosive organic compound with a sharp, pungent odor. It is an important industrial chemical mainly used in the production of:
Acrylic esters
Superabsorbent polymers
Adhesives
Coatings
Paints
Textiles
Water treatment chemicals
Acrylic acid used in various application and also as a raw material for acrylic esters in the production of resins for industrial coatings. Acrylic Acid polymer have many application in adhesives, and textiles. Viscosity Modifier; Flocculant; Maintains viscosity.
Acrylic Acid Glacial is a clear colorless liquid with pungent and non pleasant odor, it can be easily mixed with water, alcohol, ether and Chloroform.
Acrylic acid is one of the most important raw materials in:
Polymer industry
Coatings industry
Hygiene products manufacturing
Its demand continues to grow due to increasing use in superabsorbent materials and specialty chemicals.
| Porduct Name | Acrylic Acid |
| Part Number | RXSOL-19-1217-200 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| mail@rxmarine.com | |
| Website | www.rxmraine.com |
| Chemical Name | Cas No | EC No | Weight | Formula |
| Acrylic acid | 79-10-7 | 201-177-9 | 72,06 g/mol | C3H4O2 |
| Signal Word | Danger |
| Hazard Statements | H226 Flammable liquid and vapor. H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects. |
| Precautionary statements | P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| Classification of the substance or mixture | No data available |
| Supplemental Hazard Statements | No data available |
| Other hazards | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher |
| General advice | First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance |
| If inhaled | After inhalation fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen |
| Eye Contact | Rinse out with plenty of water. Remove contact lenses |
| Swallowed | Make victim drink water (two glasses at most). Consult doctor if feeling unwell. |
| Skin Contact | In case of skin contact Take off immediately all contaminated clothing. Rinse skin with water/ shower. |
| Inhalation | No data available |
| Ingestion | No data available |
| Most important symptoms and effects, both acute and delaye | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Flammability | No data available |
| Suitable extinguishing media | Water Foam Carbon dioxide (CO2) Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given |
| Special hazards arising from the substance or mixture | Carbon oxides Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire. |
| Further information | Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
|
Hazardous combustion products |
No data available |
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing |
| Protective Equipment | No data available |
| Specific Hazards Arising from the Chemical | No data available |
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
| Spillage | No data available |
| Personal Protection | Avoid dust formation. Avoid breathing vapors, mist or gas. For personal protection see section 8 |
| Enviromental Precaution | Do not let product enter drains. Risk of explosion. |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area |
| Reference to other sections | For disposal see section 13 |
| Advice on protection against fire and explosion | Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
| Incompatible materials | No data available |
| Hygiene measures | Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
| Advice on safe handling | Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. |
| Conditions for safe storage, including any incompatibilities |
No data available |
| Storage conditions | Adhere to recommended storage temperature. Crystallises at approx. +13°C. Do not store below +15°C. Risk of explosion. Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Recommended storage temperature see product label. |
| Storage class | Storage class (TRGS 510) 3 Flammable liquids |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Advice on general occupational hygiene | No data available |
| Exposure controls | Personal protective equipment |
| Engineering Control | No data available |
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
| Body Protection | Flame retardant antistatic protective clothing. |
| Skin protection | This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Viton® Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M) This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: butyl-rubber Minimum layer thickness: 0,7 mm Break through time: 30 min Material tested:Butoject® (KCL 898) |
| Respiratory protection |
Recommended Filter type Filter A-(P2) The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
|
| Other Protection Measure | No data available |
| Physical state | Liquid |
| Colour | Colorless |
| Odour | No data available |
| Odor Threshold | No data available |
| pH | No data available |
| Melting Point | 13 °C |
| Boiling Point | 141 °C at 1.013 hPa |
| Flash Point | 48,5 °C - closed cup - DIN 51755 Part 1 |
| Evaporation Rate | No data available |
| Flammability (solid, gas) | No data available |
| Explosive limits | No data available |
| Upper/lower flammability or explosive limits | No data available |
| Autoignition temperature | 438 °C at 1.013 hPa |
| Decomposition temperature | No data available |
| Vapour pressure | 5,29 hPa at 25 °C |
| Viscosity | Dynamic 1,15 mPa.s at 25 °C |
| Density | 1,05 g/cm3 at 20 °C |
| Relative Density | 1,05 at 20 °C |
| Specific Gravity | No data available |
| Partition coefficient | log Pow 0,46 at 25 °C - Bioaccumulation is not expected |
| Explosive properties | No data available |
| Solubility | 1.000 g/l at 25 °C |
| Ignition temperature | No data available |
| Particle characteristics | No data available |
| Reactivity | Vapor/air-mixtures are explosive at intense warming. |
| Chemical stability | Prolonged storage of the product can cause the stabilizer to lose its effectiveness. The product is chemically stable under standard ambient conditions (room temperature) . Contains the following stabilizer(s): hydroquinone monomethyl ether (0,02 %) |
| Possibilityof hazardous reactions | Risk of explosion with Oxidizing agents polymerisation initiators Peroxides Oxygen Violent polymerization may be caused by alkali hydroxides Amines Ammonia sulfuric acid mercaptans azides Ether Ketones Aldehydes nitrates nitrites increased reactivity with: anhydrides |
| Conditions to avoid | Avoid temperatures below recommended storage temperature. Heating. |
| Incompatible materials |
Copper, Nickel, Mild steel, Zinc
|
| Hazardous product dicomposition | No data available |
| Acute toxicity | Acute toxicity estimate Oral - 500,1 mg/kg (Calculation method) LD50 Oral - Rat - male - 1.000 - < 2.000 mg/kg (OECD Test Guideline 423) Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) Symptoms: If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach. Acute toxicity estimate Inhalation - 4 h - 11 mg/l - vapor(Calculation method) LC50 Inhalation - Rat - 4 h - 3,6 mg/l - vapor (Lit.) (Regulation (EC) No 1272/2008, Annex VI) Symptoms: mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of respiratory tract Acute toxicity estimate Dermal - 1.101 mg/kg (Calculation method) LD50 Dermal - Rabbit - male - 1.000 mg/kg (Regulation (EC) No 1272/2008, Annex VI) |
| Skin corrosion/irritation | Skin - Rabbit Result Causes severe burns. (OECD Test Guideline 404) (Regulation (EC) No 1272/2008, Annex VI) |
| Serious eye damage/irritation | Eyes - Rabbit Result: Causes burns. (IUCLID) Causes serious eye damage. |
| Respiratory or skin sensitization | Sensitisation test - Guinea pig Result negative (Lit.) |
| Carcinogenicity | No data available |
| Germ cell mutagenicity | Test Type Ames test Test system: Salmonella typhimurium Result: negative (National Toxicology Program) Test Type: In vitro mammalian cell gene mutation test Test system: Chinese hamster ovary cells Metabolic activation with and without metabolic activation Method OECD Test Guideline 476 Result negative Test Type unscheduled DNA synthesis assay Millipore- 8.00181 Page 9 of 12 The life science business of Merck operates as MilliporeSigma in the US and Canada Test system: rat hepatocytes Metabolic activation without metabolic activation Method OECD Test Guideline 482 Result negative Test Type Mutagenicity (mammal cell test) chromosome aberration. Species Rat Cell type: Bone marrow Application Route Oral Method OECD Test Guideline 475 Result negative Test Type dominant lethal test Species: Mouse Cell type Intrauterine Application Route Oral Result negative (ECHA |
| Reproductive toxicity | No data available |
| Specific target organ toxicity- single exposure |
No data available
|
| Additional Information | Assessment The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Repeated dose toxicity - Rat - male - Oral - NOAEL (No observed adverse effect level) - 40 mg/kg - LOAEL (Lowest observed adverse effect level) - 100 mg/kg burning sensation, Cough, wheezing, laryngitis, Shortness of breath, spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice. Millipore- 8.00181 Page 10 of 12 The life science business of Merck operates as MilliporeSigma in the US and Canada Liver - Irregularities - Based on Human Evidence |
| Persistence and degradability | Biodegradability Result 100 % - Readily eliminated from water (OECD Test Guideline 302B) Result 81 % - Readily biodegradable. (OECD Test Guideline 301D) |
| Toxicity to fish | Flow-through test LC50 - Oncorhynchus mykiss (rainbow trout) - 27 mg/l - 96 h (US-EPA) |
| Toxicity to daphnia and other aquatic invertebrates | Flow-through test EC50 - Daphnia magna (Water flea) - 95 mg/l - 48 h (US-EPA) |
| Toxicity | No data available |
| Toxicity to bacteria | No data available |
| Toxicity to algae | IC50 - Desmodesmus subspicatus (green algae) - 0,13 mg/l - 72 h (Regulation (EC) No. 440/2008, Annex, C.3) (IUCLID) EC10 - Desmodesmus subspicatus (green algae) - 0,03 mg/l - 72 h (Regulation (EC) No. 440/2008, Annex, C.3) (ECHA) |
| Mobility in soil | No data available |
| Results of PBT av PvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Other adverse effects | Biological effects Neutralise before sewage disposal. Discharge into the environment must be avoided. |
| Product | See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |
| Contaminated packaging | No data available |
| Waste treatment Method | No data available |
| UN number |
ADR/RID:2218 IMDG:2218 IATA:2218 |
| UN proper shipping name | ADR/RID:ACRYLIC ACID, STABILIZED IMDG:ACRYLIC ACID,STABILIZED IATA:ACRYLIC ACID, STABILIZED |
| Transport hazard classess | ADR/RID:8 (3) IMDG:8 (3) IATA:8 (3) |
| Packaging group | ADR/RID:ll IMDG:ll IATA:ll |
| Environmental hazards | ADR/RID:Yes IMDG Marine pollutant: Yes IATA: No |
| Special precautions for user | No data available |
| Further information | No data available |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 |
| Other regulations | Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | For this product a chemical safety assessment was not carried out |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
