Description
Sodium Hexameta Phosphate (SHMP or Metaphos) which is used in softening of hard water and effluent treatment by a number of textile process houses and industries.
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Sodium Hexameta Phosphate SHMP or Metaphos which is used in softening of hard water and effluent treatment by a number of textile process houses and industries.
Sodium Hexameta Phosphate (SHMP or Metaphos) which is used in softening of hard water and effluent treatment by a number of textile process houses and industries.
Colourless crystals, soluble in water. Non flammable.
Uses: Water softners, boiler water compounds, detergent, metal cleaner, paint removers, industrial cleaners.
Sodium Phosphate exporter and supplier in Mumbai, Gandhidham, Chennai, Visakhapatnam, Kolkata, Kandla, Fujairah, Ajman, Sharjah, Abudhabi, UAE, Muscat Oman, Canada, British Columbia

| Product Name | Sodium Hexa Meta Phoshphate |
| Part Number | RXSOL-33-1528-050 |
Company Details:....
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| mail@rxmarine.com | |
| Website | www.rxmraine.com |

Substances
| Synonyms |
Polyphosphate sodium salt
Calgon
Sodium polyphosphate
Phosphate glass, water soluble
|
| CAS-No | 68915-31-1 |
| EC-No. | 272-808-3 |
No components need to be disclosed according to the applicable regulations.

| Classification of the substance or mixture | Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. |
| Label elements | Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008 |
| Other hazards | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |

Description of first aid measures
| If inhaled | After inhalation: fresh air. |
| In case of skin contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower |
| In case of eye contact | After eye contact: rinse out with plenty of water. Remove contact lenses. |
| If swallowed | After swallowing: make victim drink water (two glasses at most). Consult doctor if feeling unwell. |
| Most important symptoms and effects, both acute and delayed | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |

Extinguishing media
| Suitable extinguishing media | Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Special hazards arising from the substance or mixture |
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Nitrogen oxides (NOx)
Molybdenum oxides
Not combustible.
Fire may cause evolution of:
nitrogen oxides
Ambient fire may liberate hazardous vapours.
|
| Advice for firefighters |
In the event of fire, wear self-contained breathing apparatus. |
| Further information |
Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
spray to keep fire-exposed containers cool.Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
|

| Personal precautions, protective equipment and emergency procedures |
Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.
|
| Environmental precautions | Do not let product enter drains. |
| Methods and materials for containment and cleaning up | Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts. |
| Reference to other sections | For disposal see section 13. |

| Precautions for safe handling | For precautions see section 2.2. |
| Conditions for safe storage, including any incompatibilities |
Recommended storage temperature see product label.
Recommended storage temperature see product label.Tightly closed.
Recommended storage temperature see product label.
|
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |

Control parameters
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
| Skin protection |
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Material tested:KCL 741 Dermatril® L
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Material tested:KCL 741 Dermatril® L
|
| Respiratory protection |
Required when dusts are generated.
Our recommendations on filtering respiratory protection are based on the following
standards: DIN EN 143, DIN 14387 and other accompanying standards relating to
the used respiratory protection system.
Recommended Filter type: Filter type P1
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory
protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
|
| Control of environmental exposure | Do not let product enter drains.. |

Information on basic physical and chemical properties
| Physical state | Crystalline |
| Color | No data available |
| Odor | No data available |
| Melting point/freezing point | Melting point/range: 628 °C - (External MSDS) |
| Initial boiling point and boiling range | No data available |
| Flammability (solid, gas) | The product is not flammable. |
| Upper/lower flammability or explosive limits | No data available |
| Flash point | No data available |
| Autoignition temperature | No data available |
| Decomposition temperature |
No data available
materials.Extremely flammable in the presence of the following materials or conditions: oxidizing
materials.
|
| pH |
No data available |
| Viscosity |
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
|
| Water solubility | Soluble, (experimental) |
| Partition coefficient: n-octanol/water | No data available |
| Vapor pressure | No data available |
| Density | No data available |
| Relative density | No data available |
| Relative vapor density | No data available |
| Particle characteristics | No data available |
| Explosive properties | No data available |
| Oxidizing properties | None |
| Other safety information | No data available |

| Reactivity | No data available |
| Chemical stability | The product is chemically stable under standard ambient conditions (room temperature) |
| Possibility of hazardous reactions | No data available |
| Conditions to avoid | No information available |
| Incompatible materials |
Strong acids
|
| Hazardous decomposition products | In the event of fire: see section 5 |

Information on toxicological effects
| Acute toxicity |
LD50 Oral - Rat - male and female - > 2.000 mg/kg
(OECD Test Guideline 420)
LC50 Inhalation - Rat - male and female - 4 h - > 5,05 mg/l
(OECD Test Guideline 403)
Remarks: (in analogy to similar products)
LD50 Dermal - Rat - male and female - > 2.000 mg/kg
(OECD Test Guideline 402)
Remarks: (in analogy to similar products)
The value is given in analogy to the following substances: disodium molybdate |
| Skin corrosion/irritation |
Skin - Rabbit
Result: No skin irritation - 4 h
(OECD Test Guideline 404)
Remarks: (in analogy to similar products)
The value is given in analogy to the following substances: Molybdenum dioxide
|
| Serious eye damage/eye irritation |
Eyes - Rabbit
Result: No eye irritation
(OECD Test Guideline 405)
Remarks: (in analogy to similar products)
The value is given in analogy to the following substances: Molybdenum dioxide
|
| Respiratory or skin sensitization |
Maximization Test - Guinea pig
Result: negative
(OECD Test Guideline 406)
Remarks:
(in analogy to similar products)
|
| Germ cell mutagenicity |
Test Type: Micronucleus test
Test system: Human lymphocytes
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 487
Result: negative
Remarks: (in analogy to similar products)
The value is given in analogy to the following substances: Disodium molybdate dihydrate
Test Type: Ames test
Test system: Escherichia coli/Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
Remarks: (in analogy to similar products)
The value is given in analogy to the following substances: Disodium molybdate dihydrate
Test Type: In vitro mammalian cell gene mutation test
Test system: mouse lymphoma cells
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative
Remarks: (in analogy to similar products)
The value is given in analogy to the following substances: Disodium molybdate dihydrate
|
| Carcinogenicity |
No data available
|
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure | No data available |
| Specific target organ toxicity - repeated exposure | No data available |
| Aspiration hazard | No data available |

| Persistence and degradability | No data available |
| Toxicity to fish | Static test LC50 - Oncorhynchus mykiss (rainbow trout) - 75 mg/l - 96 h (OECD Test Guideline 203) |
| Toxicity to daphnia and other aquatic invertebrates | Static test EC50 - Daphnia magna (Water flea) - 42,81 mg/l - 48 h (OECD Test Guideline 202) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: maleic acid |
| Toxicity | Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 1.520 mg/l - 96 h |
| Toxicity to bacteria | EC10 - Bacteria - 14 mg/l - 72 h Remarks: (Lit.) EC5 - E.coli - 15.000 mg/l Remarks: (Lit.) (maximum permissible toxic concentration) |
| Toxicity to algae | Static test ErC50 - Pseudokirchneriella subcapitata (green algae) - 74,35 mg/l - 72 h (OECD Test Guideline 201) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: maleic acid |
| Products Biodegradation | The methods for determining the biological degradability are not applicable to inorganic substances. |
| Mobility in soil | No data available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | No data available |
| Other adverse effects | No data available . |

| Product | Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself. |
| Contaminated packaging | Dispose of as unused product. |
| Waste treatment Method | See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |

| UN number | ADR/RID:2404 IMDG:2404 IATA: 2404 |
| UN proper shipping name | ADR/RID:PROPIONITRILE IMDG:PROPIONITRILE IATA:PROPIONITRILE |
| Transport hazard class(es) | ADR/RID: 3 (6.1) IMDG: 3 (6.1) IATA:3 (6.1) |
| Packaging group | ADR/RID: II IMDG: II IATA:II |
| Environmental hazards | ADR/RID: No IMDG: No IATA: No |
| Special precautions for user | No data available |
| Further information | Not classified as dangerous in the meaning of transport regulations. |

| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Other regulations | Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | For this product a chemical safety assessment was not carried out |

| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
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